SLANINA, Tomáš, Peter ŠEBEJ, Alexander HECKEL, Richard GIVENS and Petr KLÁN. Caged Fluoride: Photochemistry and Applications of 4-Hydroxyphenacyl Fluoride. Organic Letters. American Chemical Society, 2015, vol. 17, No 19, p. 4814-4817. ISSN 1523-7060. Available from: https://dx.doi.org/10.1021/acs.orglett.5b02374. |
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@article{1335100, author = {Slanina, Tomáš and Šebej, Peter and Heckel, Alexander and Givens, Richard and Klán, Petr}, article_number = {19}, doi = {http://dx.doi.org/10.1021/acs.orglett.5b02374}, keywords = {photochemistry; photoremovable protecting groups; fluoride}, language = {eng}, issn = {1523-7060}, journal = {Organic Letters}, title = {Caged Fluoride: Photochemistry and Applications of 4-Hydroxyphenacyl Fluoride}, url = {http://pubs.acs.org/doi/10.1021/acs.orglett.5b02374}, volume = {17}, year = {2015} }
TY - JOUR ID - 1335100 AU - Slanina, Tomáš - Šebej, Peter - Heckel, Alexander - Givens, Richard - Klán, Petr PY - 2015 TI - Caged Fluoride: Photochemistry and Applications of 4-Hydroxyphenacyl Fluoride JF - Organic Letters VL - 17 IS - 19 SP - 4814-4817 EP - 4814-4817 PB - American Chemical Society SN - 15237060 KW - photochemistry KW - photoremovable protecting groups KW - fluoride UR - http://pubs.acs.org/doi/10.1021/acs.orglett.5b02374 L2 - http://pubs.acs.org/doi/10.1021/acs.orglett.5b02374 N2 - The quantitative, efficient (Phi = 0.8) photorelease of the fluoride ion upon UV-irradiation in aqueous media is introduced. The 4-hydroxyphenacyl chromophore is simultaneously transformed into UV-transparent 4-hydroxyphenylacetate via a photo-Favorskii rearrangement. The application of this process is demonstrated by photoinduced etching of mica and silicon by AFM. ER -
SLANINA, Tomáš, Peter ŠEBEJ, Alexander HECKEL, Richard GIVENS and Petr KLÁN. Caged Fluoride: Photochemistry and Applications of 4-Hydroxyphenacyl Fluoride. \textit{Organic Letters}. American Chemical Society, 2015, vol.~17, No~19, p.~4814-4817. ISSN~1523-7060. Available from: https://dx.doi.org/10.1021/acs.orglett.5b02374.
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