| SLANINA, Tomáš, Peter ŠEBEJ, Alexander HECKEL, Richard GIVENS and Petr KLÁN. Caged Fluoride: Photochemistry and Applications of 4-Hydroxyphenacyl Fluoride. Organic Letters. American Chemical Society, 2015, vol. 17, No 19, p. 4814-4817. ISSN 1523-7060. Available from: https://dx.doi.org/10.1021/acs.orglett.5b02374. |
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@article{1335100,
author = {Slanina, Tomáš and Šebej, Peter and Heckel, Alexander and Givens, Richard and Klán, Petr},
article_number = {19},
doi = {http://dx.doi.org/10.1021/acs.orglett.5b02374},
keywords = {photochemistry; photoremovable protecting groups; fluoride},
language = {eng},
issn = {1523-7060},
journal = {Organic Letters},
title = {Caged Fluoride: Photochemistry and Applications of 4-Hydroxyphenacyl Fluoride},
url = {http://pubs.acs.org/doi/10.1021/acs.orglett.5b02374},
volume = {17},
year = {2015}
}
TY - JOUR
ID - 1335100
AU - Slanina, Tomáš - Šebej, Peter - Heckel, Alexander - Givens, Richard - Klán, Petr
PY - 2015
TI - Caged Fluoride: Photochemistry and Applications of 4-Hydroxyphenacyl Fluoride
JF - Organic Letters
VL - 17
IS - 19
SP - 4814-4817
EP - 4814-4817
PB - American Chemical Society
SN - 15237060
KW - photochemistry
KW - photoremovable protecting groups
KW - fluoride
UR - http://pubs.acs.org/doi/10.1021/acs.orglett.5b02374
L2 - http://pubs.acs.org/doi/10.1021/acs.orglett.5b02374
N2 - The quantitative, efficient (Phi = 0.8) photorelease of the fluoride ion upon UV-irradiation in aqueous media is introduced. The 4-hydroxyphenacyl chromophore is simultaneously transformed into UV-transparent 4-hydroxyphenylacetate via a photo-Favorskii rearrangement. The application of this process is demonstrated by photoinduced etching of mica and silicon by AFM.
ER -
SLANINA, Tomáš, Peter ŠEBEJ, Alexander HECKEL, Richard GIVENS and Petr KLÁN. Caged Fluoride: Photochemistry and Applications of 4-Hydroxyphenacyl Fluoride. \textit{Organic Letters}. American Chemical Society, 2015, vol.~17, No~19, p.~4814-4817. ISSN~1523-7060. Available from: https://dx.doi.org/10.1021/acs.orglett.5b02374.
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