J 2015

Caged Fluoride: Photochemistry and Applications of 4-Hydroxyphenacyl Fluoride

SLANINA, Tomáš, Peter ŠEBEJ, Alexander HECKEL, Richard GIVENS, Petr KLÁN et. al.

Basic information

Original name

Caged Fluoride: Photochemistry and Applications of 4-Hydroxyphenacyl Fluoride

Authors

SLANINA, Tomáš (203 Czech Republic, belonging to the institution), Peter ŠEBEJ (703 Slovakia, belonging to the institution), Alexander HECKEL (276 Germany), Richard GIVENS (840 United States of America) and Petr KLÁN (203 Czech Republic, guarantor, belonging to the institution)

Edition

Organic Letters, American Chemical Society, 2015, 1523-7060

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10401 Organic chemistry

Country of publisher

United States of America

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

Impact factor

Impact factor: 6.732

RIV identification code

RIV/00216224:14310/15:00081565

Organization unit

Faculty of Science

UT WoS

000362384700042

Keywords in English

photochemistry; photoremovable protecting groups; fluoride

Tags

Změněno: 11/2/2016 14:14, prof. RNDr. Petr Klán, Ph.D.

Abstract

V originále

The quantitative, efficient (Phi = 0.8) photorelease of the fluoride ion upon UV-irradiation in aqueous media is introduced. The 4-hydroxyphenacyl chromophore is simultaneously transformed into UV-transparent 4-hydroxyphenylacetate via a photo-Favorskii rearrangement. The application of this process is demonstrated by photoinduced etching of mica and silicon by AFM.

Links

GA13-25775S, research and development project
Name: Vývoj viditelným světlem aktivovatelných skupin a fluorescenčních značek pro chemii a biologii
Investor: Czech Science Foundation
LM2011028, research and development project
Name: RECETOX ? Národní infrastruktura pro výzkum toxických látek v prostředí
Investor: Ministry of Education, Youth and Sports of the CR
LO1214, research and development project
Name: Centrum pro výzkum toxických látek v prostředí (Acronym: RECETOX)
Investor: Ministry of Education, Youth and Sports of the CR