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@article{1336052,
author = {Mulder, Marie Daniëlle and Heil, Angelika and Kukučka, Petr and Kuta, Jan and Přibylová, Petra and Prokeš, Roman and Lammel, Gerhard},
article_location = {OXFORD (ENGLAND)},
article_number = {JUNE},
doi = {http://dx.doi.org/10.1016/j.atmosenv.2015.03.044},
keywords = {Long-range transport; Marine environment; Persistent organic pollutants; Mediterranean},
language = {eng},
issn = {1352-2310},
journal = {Atmospheric Environment},
title = {Long-range atmospheric transport of PAHs, PCBs and PBDEs to the central and eastern Mediterranean and changes of PCB and PBDE congener patterns in summer 2010},
url = {http://www.sciencedirect.com/science/article/pii/S135223101500268X},
volume = {111},
year = {2015}
}
TY - JOUR
ID - 1336052
AU - Mulder, Marie Daniëlle - Heil, Angelika - Kukučka, Petr - Kuta, Jan - Přibylová, Petra - Prokeš, Roman - Lammel, Gerhard
PY - 2015
TI - Long-range atmospheric transport of PAHs, PCBs and PBDEs to the central and eastern Mediterranean and changes of PCB and PBDE congener patterns in summer 2010
JF - Atmospheric Environment
VL - 111
IS - JUNE
SP - 51-59
EP - 51-59
PB - Pergamon Press
SN - 13522310
KW - Long-range transport
KW - Marine environment
KW - Persistent organic pollutants
KW - Mediterranean
UR - http://www.sciencedirect.com/science/article/pii/S135223101500268X
L2 - http://www.sciencedirect.com/science/article/pii/S135223101500268X
N2 - The central and eastern Mediterranean is a receptor area for persistent organic pollutants (POPs) emitted in western, central and eastern Europe, particularly during summer. Atmospheric concentrations of PCBs, DDXs, PBDEs, penta- and hexachlorobenzene were measured during a ship-borne survey in the summer of 2010. The concentration of PCBs (sum of 7 congeners) was 3.61 (2.08-7.72) pg m(-3), of which 6.7% was associated with the particulate phase. The mean concentration of DDT isoi-ners and their metabolites, DDE and DDD, was 2.60 (0.46-7.60) pg m(-3) (particulate mass fraction theta = 0.097), of penta- and hexachlorobenzene 0.22 (<039-2.80) pg m(-3) and 6.29 (2.48-24.16) pg m(-3), respectively, and of PBDEs (sum of 8 congeners) 7.31 (2.80-19.89) pg m(-3). The air masses studied had been transported mostly across central Europe, some crossing western Europe. The observed changes of PCB congener patterns along transport routes are in agreement with the perception that the reaction with the OH radical is dominating PCB atmospheric lifetime, and indicate an overestimation of the second order gas-phase reaction rate coefficient of PCB:153 with OH by structure-activity relationship.
ER -
MULDER, Marie Dani$\backslash$''elle, Angelika HEIL, Petr KUKUČKA, Jan KUTA, Petra PŘIBYLOVÁ, Roman PROKEŠ a Gerhard LAMMEL. Long-range atmospheric transport of PAHs, PCBs and PBDEs to the central and eastern Mediterranean and changes of PCB and PBDE congener patterns in summer 2010. \textit{Atmospheric Environment}. OXFORD (ENGLAND): Pergamon Press, roč.~111, JUNE, s.~51-59. ISSN~1352-2310. doi:10.1016/j.atmosenv.2015.03.044. 2015.
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