Ferrocene-Boronic Acid–Fructose Binding Based on Dual- Plate
Generator–Collector Voltammetry and Square-Wave Voltammetry

J 2015

Ferrocene-Boronic Acid–Fructose Binding Based on Dual- Plate Generator–Collector Voltammetry and Square-Wave Voltammetry

LI, Meng, Su-Ying XU, Andrew J. GROSS, Jules L. HAMMOND, Pedro ESTRELA et. al.

Basic information

Original name

Ferrocene-Boronic Acid–Fructose Binding Based on Dual- Plate Generator–Collector Voltammetry and Square-Wave Voltammetry

Authors

LI, Meng (826 United Kingdom of Great Britain and Northern Ireland), Su-Ying XU (826 United Kingdom of Great Britain and Northern Ireland), Andrew J. GROSS (826 United Kingdom of Great Britain and Northern Ireland), Jules L. HAMMOND (826 United Kingdom of Great Britain and Northern Ireland), Pedro ESTRELA (826 United Kingdom of Great Britain and Northern Ireland), James WEBER (826 United Kingdom of Great Britain and Northern Ireland), Karel LACINA (203 Czech Republic, guarantor, belonging to the institution), Tony D. JAMES (826 United Kingdom of Great Britain and Northern Ireland) and Frank MARKEN (826 United Kingdom of Great Britain and Northern Ireland)

Edition

ChemElectroChem, Weinheim, WILEY-V C H VERLAG GMBH, 2015, 2196-0216

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10405 Electrochemistry

Country of publisher

Germany

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Impact factor

Impact factor: 3.506

RIV identification code

RIV/00216224:14740/15:00086932

Organization unit

Central European Institute of Technology

DOI

http://dx.doi.org/10.1002/celc.201500016

UT WoS

000357862100013

Keywords in English

boronic acids; electroanalysis; ferrocene; saccharides; voltammetry

Abstract

V originále

The interaction of ferrocene-boronic acid with fructose is investigated in aqueous 0.1 M phosphate buffer at pH 7, 8 and 9. Two voltammetric methods, based on 1) a dual-plate generator–collector micro-trench electrode (steady state) and 2) a square-wave voltammetry (transient) method, are applied and compared in terms of mechanistic resolution. A combination of experimental data is employed to obtain new insights into the binding rates and the cumulative binding constants for both the reduced ferrocene-boronic acid (pH dependent and weakly binding) and for the oxidised ferrocene-boronic acid (pH independent and strongly binding).

Links

ED1.1.00/02.0068, research and development project

Name: CEITEC - central european institute of technology

Citovat

LI, Meng, Su-Ying XU, Andrew J. GROSS, Jules L. HAMMOND, Pedro ESTRELA, James WEBER, Karel LACINA, Tony D. JAMES and Frank MARKEN. Ferrocene-Boronic Acid–Fructose Binding Based on Dual- Plate Generator–Collector Voltammetry and Square-Wave Voltammetry. ChemElectroChem. Weinheim: WILEY-V C H VERLAG GMBH, 2015, vol. 2, No 6, p. 867-871. ISSN 2196-0216. Available from: https://dx.doi.org/10.1002/celc.201500016.

@article{1338621,
   author = {Li, Meng and Xu, SuandYing and Gross, Andrew J. and Hammond, Jules L. and Estrela, Pedro and Weber, James and Lacina, Karel and James, Tony D. and Marken, Frank},
   article_location = {Weinheim},
   article_number = {6},
   doi = {http://dx.doi.org/10.1002/celc.201500016},
   keywords = {boronic acids; electroanalysis; ferrocene; saccharides; voltammetry},
   language = {eng},
   issn = {2196-0216},
   journal = {ChemElectroChem},
   title = {Ferrocene-Boronic Acid–Fructose Binding Based on Dual- Plate Generator–Collector Voltammetry and Square-Wave Voltammetry},
   url = {http://onlinelibrary.wiley.com/doi/10.1002/celc.201500016/full},
   volume = {2},
   year = {2015}
}

TY  - JOUR
ID  - 1338621
AU  - Li, Meng - Xu, Su-Ying - Gross, Andrew J. - Hammond, Jules L. - Estrela, Pedro - Weber, James - Lacina, Karel - James, Tony D. - Marken, Frank
PY  - 2015
TI  - Ferrocene-Boronic Acid–Fructose Binding Based on Dual- Plate Generator–Collector Voltammetry and Square-Wave Voltammetry
JF  - ChemElectroChem
VL  - 2
IS  - 6
SP  - 867-871
EP  - 867-871
PB  - WILEY-V C H VERLAG GMBH
SN  - 21960216
KW  - boronic acids
KW  - electroanalysis
KW  - ferrocene
KW  - saccharides
KW  - voltammetry
UR  - http://onlinelibrary.wiley.com/doi/10.1002/celc.201500016/full
L2  - http://onlinelibrary.wiley.com/doi/10.1002/celc.201500016/full
N2  - The interaction of ferrocene-boronic acid with fructose is investigated in aqueous 0.1 M phosphate buffer at pH 7, 8 and 9. Two voltammetric methods, based on 1) a dual-plate generator–collector micro-trench electrode (steady state) and 2) a square-wave voltammetry (transient) method, are applied and compared in terms of mechanistic resolution. A combination of experimental data is employed to obtain new insights into the binding rates and the cumulative binding constants for both the reduced ferrocene-boronic acid (pH dependent and weakly binding) and for the oxidised ferrocene-boronic acid (pH independent and strongly binding).
ER  -

LI, Meng, Su-Ying XU, Andrew J. GROSS, Jules L. HAMMOND, Pedro ESTRELA, James WEBER, Karel LACINA, Tony D. JAMES and Frank MARKEN. Ferrocene-Boronic Acid–Fructose Binding Based on Dual- Plate Generator–Collector Voltammetry and Square-Wave Voltammetry. \textit{ChemElectroChem}. Weinheim: WILEY-V C H VERLAG GMBH, 2015, vol.~2, No~6, p.~867-871. ISSN~2196-0216. Available from: https://dx.doi.org/10.1002/celc.201500016.

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