| MANAKHOV, Anton, David NEČAS, Jan ČECHAL, David PAVLIŇÁK, Marek ELIÁŠ a Lenka ZAJÍČKOVÁ. Deposition of stable amine coating onto polycaprolactone nanofibers by low pressure cyclopropylamine plasma polymerization. Thin Solid Films. Lausanne: Elsevier science, 2015, roč. 581, APR, s. 7-13. ISSN 0040-6090. doi:10.1016/j.tsf.2014.09.015. |
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@article{1340773,
author = {Manakhov, Anton and Nečas, David and Čechal, Jan and Pavliňák, David and Eliáš, Marek and Zajíčková, Lenka},
article_location = {Lausanne},
article_number = {APR},
doi = {http://dx.doi.org/10.1016/j.tsf.2014.09.015},
keywords = {Polycaprolactone; Nanofibers; Cyclopropylamine; Plasma polymerization; Water stability; X-ray photoelectron spectroscopy},
language = {eng},
issn = {0040-6090},
journal = {Thin Solid Films},
title = {Deposition of stable amine coating onto polycaprolactone nanofibers by low pressure cyclopropylamine plasma polymerization},
url = {https://www.researchgate.net/publication/266139961_Deposition_of_stable_amine_coating_onto_polycaprolactone_nanofibers_by_low_pressure_cyclopropylamine_plasma_polymerization},
volume = {581},
year = {2015}
}
TY - JOUR
ID - 1340773
AU - Manakhov, Anton - Nečas, David - Čechal, Jan - Pavliňák, David - Eliáš, Marek - Zajíčková, Lenka
PY - 2015
TI - Deposition of stable amine coating onto polycaprolactone nanofibers by low pressure cyclopropylamine plasma polymerization
JF - Thin Solid Films
VL - 581
IS - APR
SP - 7-13
EP - 7-13
PB - Elsevier science
SN - 00406090
KW - Polycaprolactone
KW - Nanofibers
KW - Cyclopropylamine
KW - Plasma polymerization
KW - Water stability
KW - X-ray photoelectron spectroscopy
UR - https://www.researchgate.net/publication/266139961_Deposition_of_stable_amine_coating_onto_polycaprolactone_nanofibers_by_low_pressure_cyclopropylamine_plasma_polymerization
L2 - https://www.researchgate.net/publication/266139961_Deposition_of_stable_amine_coating_onto_polycaprolactone_nanofibers_by_low_pressure_cyclopropylamine_plasma_polymerization
N2 - Amine-rich films are of high interest for the bio-applications including drug delivery and tissue engineering thanks to their high reactivity allowing the formation of the covalent linkages between biomolecules and a surface. However, the bio-applications of amine-rich films require their good stability in water which is often achieved at large expenses of the amine concentration. Recently, non-toxic cyclopropylamine (CPA) has been applied for the plasma polymerization of films bearing high NHx environment combined with the moderate thickness loss (20%) afterwater immersion for 48 h. In thiswork, the amine-rich film with the NHx concentration over 7 at.% was deposited on Si substrates and polycaprolactone nanofiber meshes by using CPA plasma polymerization (pulsed mode) in a vertically oriented stainless steel reactor. The substrates were placed at the radio frequency electrode and the ion bombardment caused by direct-current self-bias was suppressed by using high pressure of 50 Pa. Analysis of samples by scanning electron microscopy did not reveal any cracks in the deposited layer formed during a sample immersion inwater. Fourier transform infrared (FTIR) spectroscopy and X-ray photoelectron spectroscopy (XPS) confirmed a slight oxidation of amine groups in water but the film still contained 5 at.% of NHx (according to the N1s XPS fitting) after the immersion. The rapid oxidation of amine groups was observed during the aging experiment carried out in air at room temperature because FTIR revealed an increase of amide peaks that increased progressivelywith aging time. However, this oxidationwas significantly reduced if the plasma polymer was stored at -20 degrees C. Since the films exhibit high amine concentration and very good water stability they have great potential for applications as biocompatible functional coatings. (C) 2014 Elsevier B.V. All rights reserved.
ER -
MANAKHOV, Anton, David NEČAS, Jan ČECHAL, David PAVLIŇÁK, Marek ELIÁŠ a Lenka ZAJÍČKOVÁ. Deposition of stable amine coating onto polycaprolactone nanofibers by low pressure cyclopropylamine plasma polymerization. \textit{Thin Solid Films}. Lausanne: Elsevier science, 2015, roč.~581, APR, s.~7-13. ISSN~0040-6090. doi:10.1016/j.tsf.2014.09.015.
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