SMRČKA, Filip, Jakub VANĚK and Přemysl LUBAL. Voltametric determination of bicarbonate. In Libuše Trnková. Abstract book of XV. Workshop of Physical Chemists and Electrochemists. Brno: Masaryk University, 2015, p. 165-168. ISBN 978-80-210-7857-4.
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Basic information
Original name Voltametric determination of bicarbonate
Authors SMRČKA, Filip (203 Czech Republic, belonging to the institution), Jakub VANĚK (203 Czech Republic, belonging to the institution) and Přemysl LUBAL (203 Czech Republic, guarantor, belonging to the institution).
Edition Brno, Abstract book of XV. Workshop of Physical Chemists and Electrochemists, p. 165-168, 4 pp. 2015.
Publisher Masaryk University
Other information
Original language English
Type of outcome Proceedings paper
Field of Study 10406 Analytical chemistry
Country of publisher Czech Republic
Confidentiality degree is not subject to a state or trade secret
Publication form printed version "print"
RIV identification code RIV/00216224:14310/15:00081672
Organization unit Faculty of Science
ISBN 978-80-210-7857-4
Keywords in English Macrocyclic ligands; Eu(III) ion; voltametry; anion determination
Tags AKR
Changed by Changed by: Ing. Andrea Mikešková, učo 137293. Changed: 28/4/2016 15:53.
Abstract
Electrochemical properties of LnIII complexes with H2DO2A and H3DO3A ligand make them perfect candidates for use in many chemical, biological and environmental systems. H2DO2A and H3DO3A are hexa- and heptadentate ligands forming very stable binary complexes with europium(III) ion, where three, resp. two coordination sites are occupied by water molecules. These complexes form ternary complexes with small tri- and bidentate ligands, e.g. carbonate, oxalate, phosphate, etc. Different stability constants of those ternary complexes can be utilized for electrochemical selective determination of anions.
Links
ED1.1.00/02.0068, research and development projectName: CEITEC - central european institute of technology
GA13-08336S, research and development projectName: Hybridní materiály založené na makrocyklických ligandech pro využití v medicíně
Investor: Czech Science Foundation
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