| AMATO, Filippo, Bhimrao Vaijnath PHULWALE, Ctibor MAZAL and Josef HAVEL. Matrix-assisted laser desorption/ionisation quadrupole ion trap time-of-flight mass spectrometry of novel shape-persistent macrocycles. Rapid Communications in Mass Spectrometry. Wiley, 2015, vol. 29, No 12, p. 1125-1134. ISSN 0951-4198. Available from: https://dx.doi.org/10.1002/rcm.7209. |
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@article{1341138,
author = {Amato, Filippo and Phulwale, Bhimrao Vaijnath and Mazal, Ctibor and Havel, Josef},
article_number = {12},
doi = {http://dx.doi.org/10.1002/rcm.7209},
keywords = {ELECTRON-TRANSFER PROCESSES; ARYLENE ETHYNYLENE MACROCYCLES; ACCEPTOR SYSTEMS; DONOR; DERIVATIVES; PRECURSORS; MOLECULES; RINGS},
language = {eng},
issn = {0951-4198},
journal = {Rapid Communications in Mass Spectrometry},
title = {Matrix-assisted laser desorption/ionisation quadrupole ion trap time-of-flight mass spectrometry of novel shape-persistent macrocycles},
url = {http://onlinelibrary.wiley.com/doi/10.1002/rcm.7209/abstract;jsessionid=AEF9160FA0CD251A41CEF867A88F6C96.f04t03},
volume = {29},
year = {2015}
}
TY - JOUR
ID - 1341138
AU - Amato, Filippo - Phulwale, Bhimrao Vaijnath - Mazal, Ctibor - Havel, Josef
PY - 2015
TI - Matrix-assisted laser desorption/ionisation quadrupole ion trap time-of-flight mass spectrometry of novel shape-persistent macrocycles
JF - Rapid Communications in Mass Spectrometry
VL - 29
IS - 12
SP - 1125-1134
EP - 1125-1134
PB - Wiley
SN - 09514198
KW - ELECTRON-TRANSFER PROCESSES
KW - ARYLENE ETHYNYLENE MACROCYCLES
KW - ACCEPTOR SYSTEMS
KW - DONOR
KW - DERIVATIVES
KW - PRECURSORS
KW - MOLECULES
KW - RINGS
UR - http://onlinelibrary.wiley.com/doi/10.1002/rcm.7209/abstract;jsessionid=AEF9160FA0CD251A41CEF867A88F6C96.f04t03
L2 - http://onlinelibrary.wiley.com/doi/10.1002/rcm.7209/abstract;jsessionid=AEF9160FA0CD251A41CEF867A88F6C96.f04t03
N2 - Shape-persistent macrocycles (SPMs) represent innovative molecular building blocks for the development of highly organised supramolecular architectures with application in nanotechnology, chemistry, catalysis and optoelectronics. Systematic mass spectrometric characterisation of SPMs and their collision-activated decay is not available to date. Characterization of alkoxy-decorated SPMs was performed by matrix-assisted laser desorption/ionization quadrupole ion trap time-of-flight mass spectrometry (MALDI-QIT-TOFMS) and collision-induced dissociation (CID). Laser excitation of SPMs leads to the formation of stable cation radicals which show characteristic fragmentation patterns. All the product ions formed were identified. Photoelectrons generated during the MALDI process and full-ring conjugation were found to be fundamental for the formation of molecular cation radicals and their stabilisation, respectively. Formation of supramolecular aggregates of SPMs by - stacking was proven. SPMs are suitable motifs for the preparation of novel fullerene-based donor-acceptor systems. Alkoxy-decorated SPMs represent promising electron-donating building blocks that can be exploited in electronics and optoelectronics for the development of robust and highly efficient laser-activated supramolecular switches.
ER -
AMATO, Filippo, Bhimrao Vaijnath PHULWALE, Ctibor MAZAL and Josef HAVEL. Matrix-assisted laser desorption/ionisation quadrupole ion trap time-of-flight mass spectrometry of novel shape-persistent macrocycles. \textit{Rapid Communications in Mass Spectrometry}. Wiley, 2015, vol.~29, No~12, p.~1125-1134. ISSN~0951-4198. Available from: https://dx.doi.org/10.1002/rcm.7209.
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