PALAO UTIEL, Eduardo, Tomáš SLANINA, Lucie MUCHOVÁ, Tomáš ŠOLOMEK, Libor VÍTEK and Petr KLÁN. Transition-Metal-Free CO-Releasing BODIPY Derivatives Activatable by Visible to NIR Light as Promising Bioactive Molecules. Journal of the American Chemical Society. WASHINGTON: American Chemical Society, 2016, vol. 138, No 1, p. 126-133. ISSN 0002-7863. Available from: https://dx.doi.org/10.1021/jacs.5b10800. |
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@article{1345773, author = {Palao Utiel, Eduardo and Slanina, Tomáš and Muchová, Lucie and Šolomek, Tomáš and Vítek, Libor and Klán, Petr}, article_location = {WASHINGTON}, article_number = {1}, doi = {http://dx.doi.org/10.1021/jacs.5b10800}, keywords = {PHOTOREMOVABLE PROTECTING GROUPS; CARBON-MONOXIDE; DESIGN STRATEGIES; ALPHA-LACTONES; GREEN LIGHT; ET-CORMS; COMPLEXES; PHOTOCORMS; ACID; DYE}, language = {eng}, issn = {0002-7863}, journal = {Journal of the American Chemical Society}, title = {Transition-Metal-Free CO-Releasing BODIPY Derivatives Activatable by Visible to NIR Light as Promising Bioactive Molecules}, url = {http://pubs.acs.org/doi/abs/10.1021/jacs.5b10800}, volume = {138}, year = {2016} }
TY - JOUR ID - 1345773 AU - Palao Utiel, Eduardo - Slanina, Tomáš - Muchová, Lucie - Šolomek, Tomáš - Vítek, Libor - Klán, Petr PY - 2016 TI - Transition-Metal-Free CO-Releasing BODIPY Derivatives Activatable by Visible to NIR Light as Promising Bioactive Molecules JF - Journal of the American Chemical Society VL - 138 IS - 1 SP - 126-133 EP - 126-133 PB - American Chemical Society SN - 00027863 KW - PHOTOREMOVABLE PROTECTING GROUPS KW - CARBON-MONOXIDE KW - DESIGN STRATEGIES KW - ALPHA-LACTONES KW - GREEN LIGHT KW - ET-CORMS KW - COMPLEXES KW - PHOTOCORMS KW - ACID KW - DYE UR - http://pubs.acs.org/doi/abs/10.1021/jacs.5b10800 L2 - http://pubs.acs.org/doi/abs/10.1021/jacs.5b10800 N2 - Carbon monoxide-releasing molecules (CORMs) are chemical agents used to administer CO as an endogenous, biologically active molecule. A precise spatial and temporal control over the CO release is the major requirement for their applications. Here, we report the synthesis and properties of a new generation of transition-metalfree carbon monoxide-releasing molecules based on BODIPY chromophores (COR-BDPs) activatable by visible-to-NIR (up to 730 nm) light. We demonstrate their performance for both in vitro and in vivo experimental settings, and we propose the mechanism of the CO release based on steady-state and transient spectroscopy experiments and quantum chemical calculations. ER -
PALAO UTIEL, Eduardo, Tomáš SLANINA, Lucie MUCHOVÁ, Tomáš ŠOLOMEK, Libor VÍTEK and Petr KLÁN. Transition-Metal-Free CO-Releasing BODIPY Derivatives Activatable by Visible to NIR Light as Promising Bioactive Molecules. \textit{Journal of the American Chemical Society}. WASHINGTON: American Chemical Society, 2016, vol.~138, No~1, p.~126-133. ISSN~0002-7863. Available from: https://dx.doi.org/10.1021/jacs.5b10800.
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