| PALAO UTIEL, Eduardo, Tomáš SLANINA, Lucie MUCHOVÁ, Tomáš ŠOLOMEK, Libor VÍTEK and Petr KLÁN. Transition-Metal-Free CO-Releasing BODIPY Derivatives Activatable by Visible to NIR Light as Promising Bioactive Molecules. Journal of the American Chemical Society. WASHINGTON: American Chemical Society, vol. 138, No 1, p. 126-133. ISSN 0002-7863. doi:10.1021/jacs.5b10800. 2016. |
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@article{1345773,
author = {Palao Utiel, Eduardo and Slanina, Tomáš and Muchová, Lucie and Šolomek, Tomáš and Vítek, Libor and Klán, Petr},
article_location = {WASHINGTON},
article_number = {1},
doi = {http://dx.doi.org/10.1021/jacs.5b10800},
keywords = {PHOTOREMOVABLE PROTECTING GROUPS; CARBON-MONOXIDE; DESIGN STRATEGIES; ALPHA-LACTONES; GREEN LIGHT; ET-CORMS; COMPLEXES; PHOTOCORMS; ACID; DYE},
language = {eng},
issn = {0002-7863},
journal = {Journal of the American Chemical Society},
title = {Transition-Metal-Free CO-Releasing BODIPY Derivatives Activatable by Visible to NIR Light as Promising Bioactive Molecules},
url = {http://pubs.acs.org/doi/abs/10.1021/jacs.5b10800},
volume = {138},
year = {2016}
}
TY - JOUR
ID - 1345773
AU - Palao Utiel, Eduardo - Slanina, Tomáš - Muchová, Lucie - Šolomek, Tomáš - Vítek, Libor - Klán, Petr
PY - 2016
TI - Transition-Metal-Free CO-Releasing BODIPY Derivatives Activatable by Visible to NIR Light as Promising Bioactive Molecules
JF - Journal of the American Chemical Society
VL - 138
IS - 1
SP - 126-133
EP - 126-133
PB - American Chemical Society
SN - 00027863
KW - PHOTOREMOVABLE PROTECTING GROUPS
KW - CARBON-MONOXIDE
KW - DESIGN STRATEGIES
KW - ALPHA-LACTONES
KW - GREEN LIGHT
KW - ET-CORMS
KW - COMPLEXES
KW - PHOTOCORMS
KW - ACID
KW - DYE
UR - http://pubs.acs.org/doi/abs/10.1021/jacs.5b10800
L2 - http://pubs.acs.org/doi/abs/10.1021/jacs.5b10800
N2 - Carbon monoxide-releasing molecules (CORMs) are chemical agents used to administer CO as an endogenous, biologically active molecule. A precise spatial and temporal control over the CO release is the major requirement for their applications. Here, we report the synthesis and properties of a new generation of transition-metalfree carbon monoxide-releasing molecules based on BODIPY chromophores (COR-BDPs) activatable by visible-to-NIR (up to 730 nm) light. We demonstrate their performance for both in vitro and in vivo experimental settings, and we propose the mechanism of the CO release based on steady-state and transient spectroscopy experiments and quantum chemical calculations.
ER -
PALAO UTIEL, Eduardo, Tomáš SLANINA, Lucie MUCHOVÁ, Tomáš ŠOLOMEK, Libor VÍTEK and Petr KLÁN. Transition-Metal-Free CO-Releasing BODIPY Derivatives Activatable by Visible to NIR Light as Promising Bioactive Molecules. \textit{Journal of the American Chemical Society}. WASHINGTON: American Chemical Society, vol.~138, No~1, p.~126-133. ISSN~0002-7863. doi:10.1021/jacs.5b10800. 2016.
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