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@article{1346345,
author = {Horní, Michal and Binar, Radim and Nečas, Marek},
article_number = {4},
doi = {http://dx.doi.org/10.1080/10426507.2015.1128922},
keywords = {Cu-I coordination; P-N-C ligands; true heterocycles},
language = {eng},
issn = {1042-6507},
journal = {Phosphorus, Sulfur, and Silicon and the related elements},
title = {Trigonal to tetrahedral transitions in Cu-I six-membered inorganic true heterocycles},
volume = {191},
year = {2016}
}
TY - JOUR
ID - 1346345
AU - Horní, Michal - Binar, Radim - Nečas, Marek
PY - 2016
TI - Trigonal to tetrahedral transitions in Cu-I six-membered inorganic true heterocycles
JF - Phosphorus, Sulfur, and Silicon and the related elements
VL - 191
IS - 4
SP - 631-632
EP - 631-632
PB - Taylor and Francis Inc.
SN - 10426507
KW - Cu-I coordination
KW - P-N-C ligands
KW - true heterocycles
N2 - A series of six-membered Cu-I true heterocycles was prepared by reactions of Cu(PPh3)(2)NO3 with deprotonated R2P(S)-NH-C(O)R' (R' = (CH2)(3)CH3, C6H5, C6H4F, C6H4Cl; R = Ph, OPh) ligands. The synthesized compounds were characterized by P-31 NMR spectroscopy and single crystal X-ray diffraction. According to quantum chemical calculations, most of the true Cu-I heterocycles with the P-N-C ligands should be tetrahedral. However, an exceptional trigonal complex was observed upon crystallization.
ER -
HORNÍ, Michal, Radim BINAR a Marek NEČAS. Trigonal to tetrahedral transitions in Cu-I six-membered inorganic true heterocycles. \textit{Phosphorus, Sulfur, and Silicon and the related elements}. Taylor and Francis Inc., roč.~191, č.~4, s.~631-632. ISSN~1042-6507. doi:10.1080/10426507.2015.1128922. 2016.
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