HORNÍ, Michal, Radim BINAR and Marek NEČAS. Trigonal to tetrahedral transitions in Cu-I six-membered inorganic true heterocycles. Phosphorus, Sulfur, and Silicon and the related elements. Taylor and Francis Inc., vol. 191, No 4, p. 631-632. ISSN 1042-6507. doi:10.1080/10426507.2015.1128922. 2016.
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Basic information
Original name Trigonal to tetrahedral transitions in Cu-I six-membered inorganic true heterocycles
Authors HORNÍ, Michal (203 Czech Republic, belonging to the institution), Radim BINAR (203 Czech Republic, belonging to the institution) and Marek NEČAS (203 Czech Republic, belonging to the institution).
Edition Phosphorus, Sulfur, and Silicon and the related elements, Taylor and Francis Inc. 2016, 1042-6507.
Other information
Original language English
Type of outcome Article in a journal
Field of Study 10402 Inorganic and nuclear chemistry
Country of publisher United Kingdom of Great Britain and Northern Ireland
Confidentiality degree is not subject to a state or trade secret
Impact factor Impact factor: 0.809
RIV identification code RIV/00216224:14310/16:00094202
Organization unit Faculty of Science
Doi http://dx.doi.org/10.1080/10426507.2015.1128922
UT WoS 000373882300019
Keywords in English Cu-I coordination; P-N-C ligands; true heterocycles
Tags AKR, rivok
Tags International impact, Reviewed
Changed by Changed by: doc. Mgr. Marek Nečas, Ph.D., učo 18809. Changed: 13/3/2018 10:19.
Abstract
A series of six-membered Cu-I true heterocycles was prepared by reactions of Cu(PPh3)(2)NO3 with deprotonated R2P(S)-NH-C(O)R' (R' = (CH2)(3)CH3, C6H5, C6H4F, C6H4Cl; R = Ph, OPh) ligands. The synthesized compounds were characterized by P-31 NMR spectroscopy and single crystal X-ray diffraction. According to quantum chemical calculations, most of the true Cu-I heterocycles with the P-N-C ligands should be tetrahedral. However, an exceptional trigonal complex was observed upon crystallization.
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