Trigonal to tetrahedral transitions in Cu-I six-membered inorganic true heterocycles

HORNÍ, Michal, Radim BINAR and Marek NEČAS. Trigonal to tetrahedral transitions in Cu-I six-membered inorganic true heterocycles. Phosphorus, Sulfur, and Silicon and the related elements. Taylor and Francis Inc., 2016, vol. 191, No 4, p. 631-632. ISSN 1042-6507. Available from: https://dx.doi.org/10.1080/10426507.2015.1128922.

Basic information

Original name

Trigonal to tetrahedral transitions in Cu-I six-membered inorganic true heterocycles

Authors

HORNÍ, Michal (203 Czech Republic, belonging to the institution), Radim BINAR (203 Czech Republic, belonging to the institution) and Marek NEČAS (203 Czech Republic, belonging to the institution)

Edition

Phosphorus, Sulfur, and Silicon and the related elements, Taylor and Francis Inc. 2016, 1042-6507

---

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

United Kingdom of Great Britain and Northern Ireland

Confidentiality degree

není předmětem státního či obchodního tajemství

Impact factor

Impact factor: 0.809

RIV identification code

RIV/00216224:14310/16:00094202

Organization unit

Faculty of Science

DOI

http://dx.doi.org/10.1080/10426507.2015.1128922

UT WoS

000373882300019

Keywords in English

Cu-I coordination; P-N-C ligands; true heterocycles

Tags

AKR, rivok

Tags

International impact, Reviewed

---

Abstract

V originále

A series of six-membered Cu-I true heterocycles was prepared by reactions of Cu(PPh3)(2)NO3 with deprotonated R2P(S)-NH-C(O)R' (R' = (CH2)(3)CH3, C6H5, C6H4F, C6H4Cl; R = Ph, OPh) ligands. The synthesized compounds were characterized by P-31 NMR spectroscopy and single crystal X-ray diffraction. According to quantum chemical calculations, most of the true Cu-I heterocycles with the P-N-C ligands should be tetrahedral. However, an exceptional trigonal complex was observed upon crystallization.