SHARMA, Vimal Kumar, David HYNEK, Libuše TRNKOVÁ, Dušan HEMZAL, Marian MÁRIK, René KIZEK and Jaromír HUBÁLEK. Electrochemical determination of adenine using a glassy carbon electrode modified with graphene oxide and polyaniline. Microchimica Acta. Wien: Springer-Verlag, 2016, vol. 183, No 4, p. 1299-1306. ISSN 0026-3672. Available from: https://dx.doi.org/10.1007/s00604-015-1740-0.
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Basic information
Original name Electrochemical determination of adenine using a glassy carbon electrode modified with graphene oxide and polyaniline
Authors SHARMA, Vimal Kumar (356 India, belonging to the institution), David HYNEK (203 Czech Republic), Libuše TRNKOVÁ (203 Czech Republic, guarantor, belonging to the institution), Dušan HEMZAL (203 Czech Republic, belonging to the institution), Marian MÁRIK (703 Slovakia), René KIZEK (203 Czech Republic) and Jaromír HUBÁLEK (203 Czech Republic).
Edition Microchimica Acta, Wien, Springer-Verlag, 2016, 0026-3672.
Other information
Original language English
Type of outcome Article in a journal
Field of Study 10403 Physical chemistry
Country of publisher Austria
Confidentiality degree is not subject to a state or trade secret
WWW URL
Impact factor Impact factor: 4.580
RIV identification code RIV/00216224:14310/16:00090238
Organization unit Faculty of Science
Doi http://dx.doi.org/10.1007/s00604-015-1740-0
UT WoS 000373146100003
Keywords (in Czech) nanokompozit; senzor; cyklická voltametrie; diferenční pulzní voltametrie; skenovací elektronová mikroskopie; Ramanova spektroskopie
Keywords in English nanocomposite; sensor; cyclic voltammetry; differential pulse voltammetry; scanning electron microscopy; Raman spectroscopy
Tags AKR, rivok
Changed by Changed by: Mgr. Marie Šípková, DiS., učo 437722. Changed: 23/4/2020 17:40.
Abstract
The electrochemical behavior of adenine at a glassy carbon electrode (GCE) modified with a nanocomposite consisting of graphene oxide and polyaniline was investigated by cyclic voltammetry and differential pulse voltammetry. The nanocomposite was synthesized by polymerization and characterized by Raman and UV-vis spectroscopy, and its morphology was examined by scanning electron microscopy. Adenine is oxidized at the modified GCE at a working potential of 1.2 V (vs. Ag/AgCl) and gives a current density of approximately 2.64 nA.cm(-2), which is distinctly increased compared to the 0.57 nA.cm(-2) of a bare electrode. Peak current and adenine concentration are linearly related to each other in the range from 0.5 mu M to 20 mu M. The modified GCE exhibits acceptable analytical performance, with a detection limit of 72 nM and a limit of quantification of 240 nM. It is excellently reproducible, stable, and fabrication is simple.
Links
EE2.3.30.0009, research and development projectName: Zaměstnáním čerstvých absolventů doktorského studia k vědecké excelenci
LH13053, research and development projectName: Chemická a elektrochemická analýza purinových derivátů a jejich komplexů s mědí (Acronym: CECAP)
Investor: Ministry of Education, Youth and Sports of the CR
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