Laser Ablation Synthesis of Gold Selenides by Using a Mass
Spectrometer as a Synthesizer: Laser Desorption Ionization
Time-of-Flight Mass Spectrometry

J 2016

Laser Ablation Synthesis of Gold Selenides by Using a Mass Spectrometer as a Synthesizer: Laser Desorption Ionization Time-of-Flight Mass Spectrometry

PROKEŠ, Lubomír, Pavel KUBÁČEK, Eladia Maria PEÑA-MÉNDEZ, Filippo AMATO, Jose Elias CONDE et. al.

Basic information

Original name

Laser Ablation Synthesis of Gold Selenides by Using a Mass Spectrometer as a Synthesizer: Laser Desorption Ionization Time-of-Flight Mass Spectrometry

Authors

PROKEŠ, Lubomír (203 Czech Republic, belonging to the institution), Pavel KUBÁČEK (203 Czech Republic, belonging to the institution), Eladia Maria PEÑA-MÉNDEZ (724 Spain), Filippo AMATO (380 Italy, belonging to the institution), Jose Elias CONDE (724 Spain), Milan ALBERTI (203 Czech Republic, guarantor, belonging to the institution) and Josef HAVEL (203 Czech Republic, belonging to the institution)

Edition

Chemistry – A European Journal, Weinheim, Wiley, 2016, 0947-6539

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10406 Analytical chemistry

Country of publisher

Germany

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Impact factor

Impact factor: 5.317

RIV identification code

RIV/00216224:14310/16:00088087

Organization unit

Faculty of Science

DOI

http://dx.doi.org/10.1002/chem.201600160

UT WoS

000382918700025

Keywords in English

laser ablation synthesis; gold selenides; LDI-TOF; clusters; mass spectrometry

Abstract

V originále

Methods for the rapid construction of new chemical motifs have the potential to accelerate the development of nanoscience. The synthesis of new chemical entities by laser ablation has been systematically demonstrated by using mixtures of gold and selenium. The compounds generated are detected by time-of-flight mass spectrometry and, for selected compounds, the structure is investigated by using density functional theory optimization. In total, 67 new gold selenide clusters have been synthesized, demonstrating an unsuspected richness in gold chemistry. Chemical species generated in the gas phase might inspire new routes for the synthesis of novel compounds in the solid state.

Links

ED2.1.00/03.0086, research and development project

Name: Regionální VaV centrum pro nízkonákladové plazmové a nanotechnologické povrchové úpravy

GA13-05082S, research and development project

Name: Analýza a aplikace plazmatických procesů pro přípravu tenkých vrstev amorfních chalkogenidů

Investor: Czech Science Foundation

LO1411, research and development project

Name: Rozvoj centra pro nízkonákladové plazmové a nanotechnologické povrchové úpravy (Acronym: CEPLANT plus)

Investor: Ministry of Education, Youth and Sports of the CR

Citovat

PROKEŠ, Lubomír, Pavel KUBÁČEK, Eladia Maria PEÑA-MÉNDEZ, Filippo AMATO, Jose Elias CONDE, Milan ALBERTI and Josef HAVEL. Laser Ablation Synthesis of Gold Selenides by Using a Mass Spectrometer as a Synthesizer: Laser Desorption Ionization Time-of-Flight Mass Spectrometry. Chemistry – A European Journal. Weinheim: Wiley, 2016, vol. 22, No 32, p. 11261-11268. ISSN 0947-6539. Available from: https://dx.doi.org/10.1002/chem.201600160.

@article{1352176,
   author = {Prokeš, Lubomír and Kubáček, Pavel and PeñaandMéndez, Eladia Maria and Amato, Filippo and Conde, Jose Elias and Alberti, Milan and Havel, Josef},
   article_location = {Weinheim},
   article_number = {32},
   doi = {http://dx.doi.org/10.1002/chem.201600160},
   keywords = {laser ablation synthesis; gold selenides; LDI-TOF; clusters; mass spectrometry},
   language = {eng},
   issn = {0947-6539},
   journal = {Chemistry – A European Journal},
   title = {Laser Ablation Synthesis of Gold Selenides by Using a Mass Spectrometer as a Synthesizer: Laser Desorption Ionization Time-of-Flight Mass Spectrometry},
   url = {http://onlinelibrary.wiley.com/doi/10.1002/chem.201600160/full},
   volume = {22},
   year = {2016}
}

TY  - JOUR
ID  - 1352176
AU  - Prokeš, Lubomír - Kubáček, Pavel - Peña-Méndez, Eladia Maria - Amato, Filippo - Conde, Jose Elias - Alberti, Milan - Havel, Josef
PY  - 2016
TI  - Laser Ablation Synthesis of Gold Selenides by Using a Mass Spectrometer as a Synthesizer: Laser Desorption Ionization Time-of-Flight Mass Spectrometry
JF  - Chemistry – A European Journal
VL  - 22
IS  - 32
SP  - 11261-11268
EP  - 11261-11268
PB  - Wiley
SN  - 09476539
KW  - laser ablation synthesis
KW  - gold selenides
KW  - LDI-TOF
KW  - clusters
KW  - mass spectrometry
UR  - http://onlinelibrary.wiley.com/doi/10.1002/chem.201600160/full
N2  - Methods for the rapid construction of new chemical motifs have the potential to accelerate the development of nanoscience. The synthesis of new chemical entities by laser ablation has been systematically demonstrated by using mixtures of gold and selenium. The compounds generated are detected by time-of-flight mass spectrometry and, for selected compounds, the structure is investigated by using density functional theory optimization. In total, 67 new gold selenide clusters have been synthesized, demonstrating an unsuspected richness in gold chemistry. Chemical species generated in the gas phase might inspire new routes for the synthesis of novel compounds in the solid state.
ER  -

PROKEŠ, Lubomír, Pavel KUBÁČEK, Eladia Maria PEÑA-MÉNDEZ, Filippo AMATO, Jose Elias CONDE, Milan ALBERTI and Josef HAVEL. Laser Ablation Synthesis of Gold Selenides by Using a Mass Spectrometer as a Synthesizer: Laser Desorption Ionization Time-of-Flight Mass Spectrometry. \textit{Chemistry – A European Journal}. Weinheim: Wiley, 2016, vol.~22, No~32, p.~11261-11268. ISSN~0947-6539. Available from: https://dx.doi.org/10.1002/chem.201600160.

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