Synthesis of Tin (IV) Heteroarylalkenols and Their Susceptibility Towards Fluorination

PODHORSKÝ, Ján, Zdeněk MORAVEC, Jiří PINKAS, Corrina HEGEMANN and Sanjay MATHUR. Synthesis of Tin (IV) Heteroarylalkenols and Their Susceptibility Towards Fluorination. In 15th International Conference on the Coordination and Organometallic Chemistry of Germanium, Tin and Lead. 2016. ISBN 978-80-7560-007-3.

Basic information

Original name

Synthesis of Tin (IV) Heteroarylalkenols and Their Susceptibility Towards Fluorination

Name in Czech

Syntézy heteroarylalketonátů ciničitých a jejich reaktivita s fluoračními činidly

Authors

PODHORSKÝ, Ján, Zdeněk MORAVEC, Jiří PINKAS, Corrina HEGEMANN and Sanjay MATHUR

Edition

15th International Conference on the Coordination and Organometallic Chemistry of Germanium, Tin and Lead, 2016

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Other information

Language

English

Type of outcome

Konferenční abstrakt

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

Czech Republic

Confidentiality degree

není předmětem státního či obchodního tajemství

Organization unit

Faculty of Science

ISBN

978-80-7560-007-3

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Abstract

V originále

In our work, we focused on reactions of organometallic tin (IV) precursors, such as Sn(OtBu)4, Me3SnCl, and Me3SnF, with β-heteroarylalketonates: 3,3,3-trifluoro(pyridin-2-yl)propen-2-ol, 3,3,3-trifluoro(dimethyl-1,3-oxazol-2-yl)propen-2-ol, and 3,3,3-trifluoro(1,3-benzthiazol-2- yl)propen-2-ol. Obtained compounds were exposed to various fluorination agents (HF, XeF2, and NH4F) and their reactivity towards them was compared to already published Sn (II) β-heteroarylalketonates, in order to determine their suitability as possible FTO precursors.