Synthesis and characterization of lanthanide complexes with a
pentadentate triazine-based ligand

J 2016

Synthesis and characterization of lanthanide complexes with a pentadentate triazine-based ligand

PAVELEK, Lubomír, Vít LADÁNYI, Marek NEČAS, Zdeněk MORAVEC, Kamil WICHTERLE et. al.

Basic information

Original name

Synthesis and characterization of lanthanide complexes with a pentadentate triazine-based ligand

Authors

PAVELEK, Lubomír (203 Czech Republic), Vít LADÁNYI (203 Czech Republic, belonging to the institution), Marek NEČAS (203 Czech Republic, guarantor, belonging to the institution), Zdeněk MORAVEC (203 Czech Republic, belonging to the institution) and Kamil WICHTERLE (203 Czech Republic)

Edition

Polyhedron, Spojené království, Pergamon Press, 2016, 0277-5387

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

United Kingdom of Great Britain and Northern Ireland

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Impact factor

Impact factor: 1.926

RIV identification code

RIV/00216224:14310/16:00090883

Organization unit

Faculty of Science

DOI

http://dx.doi.org/10.1016/j.poly.2016.08.035

UT WoS

000389165400016

Keywords in English

Lanthanide complexes; Triazine ligands; X-ray structure; Optical properties; Thermal analysis

Abstract

V originále

The article reports on the synthesis of eight newly prepared complexes with previously prepared organic ligand. The lanthanide complexes were characterized by single-crystal X-ray diffraction, UV–Vis, fluorescence and IR spectroscopy. Thermal decomposition of the two terbium(III) complexes with different solvent in their coordination sphere were investigated using thermogravimetric analysis. The lanthanide complexes are insoluble in water and are soluble in DMF and DMSO. This study contributes to the understanding of the coordination behaviour of the lanthanide(III) ions in organic polydentate ligand.

Links

LM2015043, research and development project

Name: Česká infrastruktura pro integrativní strukturní biologii (Acronym: CIISB)

Investor: Ministry of Education, Youth and Sports of the CR

LQ1601, research and development project

Name: CEITEC 2020 (Acronym: CEITEC2020)

Investor: Ministry of Education, Youth and Sports of the CR

Citovat

PAVELEK, Lubomír, Vít LADÁNYI, Marek NEČAS, Zdeněk MORAVEC and Kamil WICHTERLE. Synthesis and characterization of lanthanide complexes with a pentadentate triazine-based ligand. Polyhedron. Spojené království: Pergamon Press, 2016, vol. 119, November, p. 134-141. ISSN 0277-5387. Available from: https://dx.doi.org/10.1016/j.poly.2016.08.035.

@article{1354654,
   author = {Pavelek, Lubomír and Ladányi, Vít and Nečas, Marek and Moravec, Zdeněk and Wichterle, Kamil},
   article_location = {Spojené království},
   article_number = {November},
   doi = {http://dx.doi.org/10.1016/j.poly.2016.08.035},
   keywords = {Lanthanide complexes; Triazine ligands; X-ray structure; Optical properties; Thermal analysis},
   language = {eng},
   issn = {0277-5387},
   journal = {Polyhedron},
   title = {Synthesis and characterization of lanthanide complexes with a pentadentate triazine-based ligand},
   url = {http://www.sciencedirect.com/science/article/pii/S0277538716303941},
   volume = {119},
   year = {2016}
}

TY  - JOUR
ID  - 1354654
AU  - Pavelek, Lubomír - Ladányi, Vít - Nečas, Marek - Moravec, Zdeněk - Wichterle, Kamil
PY  - 2016
TI  - Synthesis and characterization of lanthanide complexes with a pentadentate triazine-based ligand
JF  - Polyhedron
VL  - 119
IS  - November
SP  - 134-141
EP  - 134-141
PB  - Pergamon Press
SN  - 02775387
KW  - Lanthanide complexes
KW  - Triazine ligands
KW  - X-ray structure
KW  - Optical properties
KW  - Thermal analysis
UR  - http://www.sciencedirect.com/science/article/pii/S0277538716303941
L2  - http://www.sciencedirect.com/science/article/pii/S0277538716303941
N2  - The article reports on the synthesis of eight newly prepared complexes with previously prepared organic ligand. The lanthanide complexes were characterized by single-crystal X-ray diffraction, UV–Vis, fluorescence and IR spectroscopy. Thermal decomposition of the two terbium(III) complexes with different solvent in their coordination sphere were investigated using thermogravimetric analysis. The lanthanide complexes are insoluble in water and are soluble in DMF and DMSO. This study contributes to the understanding of the coordination behaviour of the lanthanide(III) ions in organic polydentate ligand.
ER  -

PAVELEK, Lubomír, Vít LADÁNYI, Marek NEČAS, Zdeněk MORAVEC and Kamil WICHTERLE. Synthesis and characterization of lanthanide complexes with a pentadentate triazine-based ligand. \textit{Polyhedron}. Spojené království: Pergamon Press, 2016, vol.~119, November, p.~134-141. ISSN~0277-5387. Available from: https://dx.doi.org/10.1016/j.poly.2016.08.035.

Detailed Information on Publication Record