| PALAO UTIEL, Eduardo, Tomáš SLANINA and Petr KLÁN. Construction of the carbon-chalcogen (S, Se, Te) bond at the 2,6-positions of BODIPY via Stille cross-coupling reaction. Chemical communications. Cambridge: Royal Society of Chemistry, 2016, vol. 52, No 80, p. 11951-11954. ISSN 1359-7345. Available from: https://dx.doi.org/10.1039/c6cc06923a. |
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@article{1369916,
author = {Palao Utiel, Eduardo and Slanina, Tomáš and Klán, Petr},
article_location = {Cambridge},
article_number = {80},
doi = {http://dx.doi.org/10.1039/c6cc06923a},
keywords = {INTRAMOLECULAR CHARGE-TRANSFER; TRIPLET EXCITED-STATE; SINGLET OXYGEN GENERATION; LARGE STOKES SHIFTS; BORON-DIPYRROMETHENE; PHOTOPHYSICAL PROPERTIES; LIVING CELLS; DYES; DERIVATIVES; FUNCTIONALIZATION},
language = {eng},
issn = {1359-7345},
journal = {Chemical communications},
title = {Construction of the carbon-chalcogen (S, Se, Te) bond at the 2,6-positions of BODIPY via Stille cross-coupling reaction},
url = {http://pubs.rsc.org/en/Content/ArticleLanding/2016/CC/C6CC06923A#!divAbstract},
volume = {52},
year = {2016}
}
TY - JOUR
ID - 1369916
AU - Palao Utiel, Eduardo - Slanina, Tomáš - Klán, Petr
PY - 2016
TI - Construction of the carbon-chalcogen (S, Se, Te) bond at the 2,6-positions of BODIPY via Stille cross-coupling reaction
JF - Chemical communications
VL - 52
IS - 80
SP - 11951-11954
EP - 11951-11954
PB - Royal Society of Chemistry
SN - 13597345
KW - INTRAMOLECULAR CHARGE-TRANSFER
KW - TRIPLET EXCITED-STATE
KW - SINGLET OXYGEN GENERATION
KW - LARGE STOKES SHIFTS
KW - BORON-DIPYRROMETHENE
KW - PHOTOPHYSICAL PROPERTIES
KW - LIVING CELLS
KW - DYES
KW - DERIVATIVES
KW - FUNCTIONALIZATION
UR - http://pubs.rsc.org/en/Content/ArticleLanding/2016/CC/C6CC06923A#!divAbstract
L2 - http://pubs.rsc.org/en/Content/ArticleLanding/2016/CC/C6CC06923A#!divAbstract
N2 - Seven new 2-chalcogen-or 2,6-dichalcogen-(S, Se, Te) BODIPY derivatives were synthesized in good to excellent yields (55-95%) by a Pd-catalyzed C-heteroatom Stille cross-coupling reaction, overcoming the limitations of SNAr. The fluorophores show interesting tunable optical properties associated with the formation of a twisted intramolecular charge transfer excited state and competing intersystem crossing.
ER -
PALAO UTIEL, Eduardo, Tomáš SLANINA and Petr KLÁN. Construction of the carbon-chalcogen (S, Se, Te) bond at the 2,6-positions of BODIPY via Stille cross-coupling reaction. \textit{Chemical communications}. Cambridge: Royal Society of Chemistry, 2016, vol.~52, No~80, p.~11951-11954. ISSN~1359-7345. Available from: https://dx.doi.org/10.1039/c6cc06923a.
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