FIALA, Tomáš and Vladimír ŠINDELÁŘ. Supramolecular complexes of bambusurils with dialkyl phosphates. Supramolecular Chemistry. ABINGDON: Taylor & Francis, 2016, vol. 28, 9-10, p. 810-816. ISSN 1061-0278. Available from: https://dx.doi.org/10.1080/10610278.2016.1146278.
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Basic information
Original name Supramolecular complexes of bambusurils with dialkyl phosphates
Authors FIALA, Tomáš (203 Czech Republic, belonging to the institution) and Vladimír ŠINDELÁŘ (203 Czech Republic, guarantor, belonging to the institution).
Edition Supramolecular Chemistry, ABINGDON, Taylor & Francis, 2016, 1061-0278.
Other information
Original language English
Type of outcome Article in a journal
Field of Study 10401 Organic chemistry
Country of publisher United Kingdom of Great Britain and Northern Ireland
Confidentiality degree is not subject to a state or trade secret
WWW URL
Impact factor Impact factor: 1.264
RIV identification code RIV/00216224:14310/16:00093209
Organization unit Faculty of Science
Doi http://dx.doi.org/10.1080/10610278.2016.1146278
UT WoS 000386329600012
Keywords in English Host-guest systems; bambusurils; organic phosphates; anion binding; macrocycles
Tags AKR, rivok
Changed by Changed by: Mgr. Michaela Hylsová, Ph.D., učo 211937. Changed: 27/1/2017 11:14.
Abstract
H-1 NMR spectrometry and X-ray diffraction were used to investigate supramolecular complexes of bambusurils and dialkyl phosphates. It was shown that bambusuril forms external complexes of 1:1 stoichiometry with dialkyl phosphates in chloroform solution. Conversely, a 2:1 complex was observed in the solid state in which each of the opposed macrocycle portals is occupied by one phosphate anion. Exclusive preference of external over inclusion binding of organic phosphates with bambusuril precludes these complexes to be used for the preparation of interlocked structures.
Links
LO1214, research and development projectName: Centrum pro výzkum toxických látek v prostředí (Acronym: RECETOX)
Investor: Ministry of Education, Youth and Sports of the CR
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