Detailed Information on Publication Record
2016
Supramolecular complexes of bambusurils with dialkyl phosphates
FIALA, Tomáš and Vladimír ŠINDELÁŘBasic information
Original name
Supramolecular complexes of bambusurils with dialkyl phosphates
Authors
FIALA, Tomáš (203 Czech Republic, belonging to the institution) and Vladimír ŠINDELÁŘ (203 Czech Republic, guarantor, belonging to the institution)
Edition
Supramolecular Chemistry, ABINGDON, Taylor & Francis, 2016, 1061-0278
Other information
Language
English
Type of outcome
Článek v odborném periodiku
Field of Study
10401 Organic chemistry
Country of publisher
United Kingdom of Great Britain and Northern Ireland
Confidentiality degree
není předmětem státního či obchodního tajemství
References:
Impact factor
Impact factor: 1.264
RIV identification code
RIV/00216224:14310/16:00093209
Organization unit
Faculty of Science
UT WoS
000386329600012
Keywords in English
Host-guest systems; bambusurils; organic phosphates; anion binding; macrocycles
Změněno: 27/1/2017 11:14, Mgr. Michaela Hylsová, Ph.D.
Abstract
V originále
H-1 NMR spectrometry and X-ray diffraction were used to investigate supramolecular complexes of bambusurils and dialkyl phosphates. It was shown that bambusuril forms external complexes of 1:1 stoichiometry with dialkyl phosphates in chloroform solution. Conversely, a 2:1 complex was observed in the solid state in which each of the opposed macrocycle portals is occupied by one phosphate anion. Exclusive preference of external over inclusion binding of organic phosphates with bambusuril precludes these complexes to be used for the preparation of interlocked structures.
Links
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