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@article{1369951,
author = {Meyer, Andreas Uwe and Straková, Karolína and Slanina, Tomáš and König, Burkhard},
article_location = {WEINHEIM},
article_number = {25},
doi = {http://dx.doi.org/10.1002/chem.201601000},
keywords = {alkyl sulfinates; photocatalysis; reaction mechanisms; transient spectroscopy; vinyl sulfones},
language = {eng},
issn = {0947-6539},
journal = {Chemistry - A European Journal},
title = {Eosin Y (EY) Photoredox-Catalyzed Sulfonylation of Alkenes: Scope and Mechanism},
url = {http://onlinelibrary.wiley.com/doi/10.1002/chem.201601000/abstract?systemMessage=WOL+Usage+report+download+page+will+be+unavailable+on+Friday+27th+January+2017+at+23%3A00+GMT%2F+18%3A00+EST%2F+07%3A00+SGT+%28Saturday+28th+Jan+for+SGT%29++for+up+to+2+hour},
volume = {22},
year = {2016}
}
TY - JOUR
ID - 1369951
AU - Meyer, Andreas Uwe - Straková, Karolína - Slanina, Tomáš - König, Burkhard
PY - 2016
TI - Eosin Y (EY) Photoredox-Catalyzed Sulfonylation of Alkenes: Scope and Mechanism
JF - Chemistry - A European Journal
VL - 22
IS - 25
SP - 8694-8699
EP - 8694-8699
PB - Wiley
SN - 09476539
KW - alkyl sulfinates
KW - photocatalysis
KW - reaction mechanisms
KW - transient spectroscopy
KW - vinyl sulfones
UR - http://onlinelibrary.wiley.com/doi/10.1002/chem.201601000/abstract?systemMessage=WOL+Usage+report+download+page+will+be+unavailable+on+Friday+27th+January+2017+at+23%3A00+GMT%2F+18%3A00+EST%2F+07%3A00+SGT+%28Saturday+28th+Jan+for+SGT%29++for+up+to+2+hour
L2 - http://onlinelibrary.wiley.com/doi/10.1002/chem.201601000/abstract?systemMessage=WOL+Usage+report+download+page+will+be+unavailable+on+Friday+27th+January+2017+at+23%3A00+GMT%2F+18%3A00+EST%2F+07%3A00+SGT+%28Saturday+28th+Jan+for+SGT%29++for+up+to+2+hour
N2 - Alkyl- and aryl vinyl sulfones were obtained by eosin Y (EY)-mediated visible-light photooxidation of sulfinate salts and the reaction of the resulting S-centered radicals with alkenes. Optimized reaction conditions, the sulfinate and alkene scope, and X-ray structural analyses of several reaction products are provided. A detailed spectroscopic study explains the reaction mechanism, which proceeds through the EY radical cation as key intermediate oxidizing the sulfinate salts.
ER -
MEYER, Andreas Uwe, Karolína STRAKOVÁ, Tomáš SLANINA a Burkhard KÖNIG. Eosin Y (EY) Photoredox-Catalyzed Sulfonylation of Alkenes: Scope and Mechanism. \textit{Chemistry - A European Journal}. WEINHEIM: Wiley, roč.~22, č.~25, s.~8694-8699. ISSN~0947-6539. doi:10.1002/chem.201601000. 2016.
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