Bidirectional air-sea exchange and accumulation of POPs (PAHs,
PCBs, OCPs and PBDEs) in the nocturnal marine boundary layer

J 2016

Bidirectional air-sea exchange and accumulation of POPs (PAHs, PCBs, OCPs and PBDEs) in the nocturnal marine boundary layer

LAMMEL, Gerhard, Franz X. MEIXNER, Branislav VRANA, Christos EFSTATHIOU, Jiří KOHOUTEK et. al.

Basic information

Original name

Bidirectional air-sea exchange and accumulation of POPs (PAHs, PCBs, OCPs and PBDEs) in the nocturnal marine boundary layer

Authors

LAMMEL, Gerhard (276 Germany, guarantor, belonging to the institution), Franz X. MEIXNER (276 Germany), Branislav VRANA (703 Slovakia, belonging to the institution), Christos EFSTATHIOU (300 Greece, belonging to the institution), Jiří KOHOUTEK (203 Czech Republic, belonging to the institution), Petr KUKUČKA (203 Czech Republic, belonging to the institution), Marie Daniëlle MULDER (528 Netherlands, belonging to the institution), Petra PŘIBYLOVÁ (203 Czech Republic, belonging to the institution), Roman PROKEŠ (203 Czech Republic, belonging to the institution), Tatsiana RUSINA (112 Belarus, belonging to the institution), Guo-Zheng SONG (276 Germany) and Manolis TSAPAKIS (300 Greece)

Edition

Atmospheric Chemistry and Physics, GOTTINGEN, European Geosciences Union, 2016, 1680-7316

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10500 1.5. Earth and related environmental sciences

Country of publisher

Germany

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Impact factor

Impact factor: 5.318

RIV identification code

RIV/00216224:14310/16:00088646

Organization unit

Faculty of Science

DOI

http://dx.doi.org/10.5194/acp-16-6381-2016

UT WoS

000378354100021

Keywords in English

POLYCYCLIC AROMATIC-HYDROCARBONS; WATER GAS-EXCHANGE; POLYBROMINATED DIPHENYL ETHERS; PERSISTENT ORGANIC POLLUTANTS; PASSIVE SAMPLING DEVICES; POLYCHLORINATED-BIPHENYLS; DRY DEPOSITION; MEDITERRANEAN-SEA; ATMOSPHERIC OCCURRENCE; BACKGROUND ATMOSPHERE

Abstract

V originále

As a consequence of long-range transported pollution, air-sea exchange can become a major source of persistent organic pollutants in remote marine environments. The vertical gradients in the air were quantified for 14 species, i.e. four parent polycyclic aromatic hydrocarbons (PAHs), three polychlorinated biphenyls (PCBs), three organochlorine pesticides (OCPs) and two polybrominated diphenylethers (PBDEs) in the gas-phase at a remote coastal site in the southern Aegean Sea in summer. Most vertical gradients were positive (Delta ca center dot Delta z > 0), indicating downward (net depositional) flux. Significant upward (net volatilisational) fluxes were found for three PAHs, mostly during daytime, and for two OCPs, mostly during night-time, as well as for one PCB and one PBDE during part of the measurements. While phenanthrene was deposited, fluoranthene (FLT) and pyrene (PYR) seem to undergo flux oscillation, hereby not following a day-night cycle. Box modelling confirms that volatilisation from the sea surface has significantly contributed to the night-time maxima of OCPs. Fluxes were quantified based on eddy covariance. Deposition fluxes ranged from -28.5 to +1.8aEuro-A mu gaEuro-m(-2)aEuro-day(-1) for PAHs and -3.4 to +0.9aEuro-A mu gaEuro-m(-2)aEuro-day(-1) for halogenated compounds. Dry particle deposition of FLT and PYR did not contribute significantly to the vertical flux.

Links

GAP503/11/1230, research and development project

Name: Perzistentní organické polutanty v atmosférických aerosolech: Procesy, které ovlivňují dálkový transport v Evropě.

Investor: Czech Science Foundation

LM2015051, research and development project

Name: Centrum pro výzkum toxických látek v prostředí (Acronym: RECETOX RI)

Investor: Ministry of Education, Youth and Sports of the CR

LO1214, research and development project

Name: Centrum pro výzkum toxických látek v prostředí (Acronym: RECETOX)

Investor: Ministry of Education, Youth and Sports of the CR

Citovat

LAMMEL, Gerhard, Franz X. MEIXNER, Branislav VRANA, Christos EFSTATHIOU, Jiří KOHOUTEK, Petr KUKUČKA, Marie Daniëlle MULDER, Petra PŘIBYLOVÁ, Roman PROKEŠ, Tatsiana RUSINA, Guo-Zheng SONG and Manolis TSAPAKIS. Bidirectional air-sea exchange and accumulation of POPs (PAHs, PCBs, OCPs and PBDEs) in the nocturnal marine boundary layer. Atmospheric Chemistry and Physics. GOTTINGEN: European Geosciences Union, 2016, vol. 16, No 10, p. 6381-6393. ISSN 1680-7316. Available from: https://dx.doi.org/10.5194/acp-16-6381-2016.

@article{1371789,
   author = {Lammel, Gerhard and Meixner, Franz X. and Vrana, Branislav and Efstathiou, Christos and Kohoutek, Jiří and Kukučka, Petr and Mulder, Marie Daniëlle and Přibylová, Petra and Prokeš, Roman and Rusina, Tatsiana and Song, GuoandZheng and Tsapakis, Manolis},
   article_location = {GOTTINGEN},
   article_number = {10},
   doi = {http://dx.doi.org/10.5194/acp-16-6381-2016},
   keywords = {POLYCYCLIC AROMATIC-HYDROCARBONS; WATER GAS-EXCHANGE; POLYBROMINATED DIPHENYL ETHERS; PERSISTENT ORGANIC POLLUTANTS; PASSIVE SAMPLING DEVICES; POLYCHLORINATED-BIPHENYLS; DRY DEPOSITION; MEDITERRANEAN-SEA; ATMOSPHERIC OCCURRENCE; BACKGROUND ATMOSPHERE},
   language = {eng},
   issn = {1680-7316},
   journal = {Atmospheric Chemistry and Physics},
   title = {Bidirectional air-sea exchange and accumulation of POPs (PAHs, PCBs, OCPs and PBDEs) in the nocturnal marine boundary layer},
   url = {http://www.atmos-chem-phys.net/16/6381/2016/},
   volume = {16},
   year = {2016}
}

TY  - JOUR
ID  - 1371789
AU  - Lammel, Gerhard - Meixner, Franz X. - Vrana, Branislav - Efstathiou, Christos - Kohoutek, Jiří - Kukučka, Petr - Mulder, Marie Daniëlle - Přibylová, Petra - Prokeš, Roman - Rusina, Tatsiana - Song, Guo-Zheng - Tsapakis, Manolis
PY  - 2016
TI  - Bidirectional air-sea exchange and accumulation of POPs (PAHs, PCBs, OCPs and PBDEs) in the nocturnal marine boundary layer
JF  - Atmospheric Chemistry and Physics
VL  - 16
IS  - 10
SP  - 6381-6393
EP  - 6381-6393
PB  - European Geosciences Union
SN  - 16807316
KW  - POLYCYCLIC AROMATIC-HYDROCARBONS
KW  - WATER GAS-EXCHANGE
KW  - POLYBROMINATED DIPHENYL ETHERS
KW  - PERSISTENT ORGANIC POLLUTANTS
KW  - PASSIVE SAMPLING DEVICES
KW  - POLYCHLORINATED-BIPHENYLS
KW  - DRY DEPOSITION
KW  - MEDITERRANEAN-SEA
KW  - ATMOSPHERIC OCCURRENCE
KW  - BACKGROUND ATMOSPHERE
UR  - http://www.atmos-chem-phys.net/16/6381/2016/
L2  - http://www.atmos-chem-phys.net/16/6381/2016/
N2  - As a consequence of long-range transported pollution, air-sea exchange can become a major source of persistent organic pollutants in remote marine environments. The vertical gradients in the air were quantified for 14 species, i.e. four parent polycyclic aromatic hydrocarbons (PAHs), three polychlorinated biphenyls (PCBs), three organochlorine pesticides (OCPs) and two polybrominated diphenylethers (PBDEs) in the gas-phase at a remote coastal site in the southern Aegean Sea in summer. Most vertical gradients were positive (Delta ca center dot Delta z > 0), indicating downward (net depositional) flux. Significant upward (net volatilisational) fluxes were found for three PAHs, mostly during daytime, and for two OCPs, mostly during night-time, as well as for one PCB and one PBDE during part of the measurements. While phenanthrene was deposited, fluoranthene (FLT) and pyrene (PYR) seem to undergo flux oscillation, hereby not following a day-night cycle. Box modelling confirms that volatilisation from the sea surface has significantly contributed to the night-time maxima of OCPs. Fluxes were quantified based on eddy covariance. Deposition fluxes ranged from -28.5 to +1.8aEuro-A mu gaEuro-m(-2)aEuro-day(-1) for PAHs and -3.4 to +0.9aEuro-A mu gaEuro-m(-2)aEuro-day(-1) for halogenated compounds. Dry particle deposition of FLT and PYR did not contribute significantly to the vertical flux.
ER  -

LAMMEL, Gerhard, Franz X. MEIXNER, Branislav VRANA, Christos EFSTATHIOU, Jiří KOHOUTEK, Petr KUKUČKA, Marie Dani$\backslash$''elle MULDER, Petra PŘIBYLOVÁ, Roman PROKEŠ, Tatsiana RUSINA, Guo-Zheng SONG and Manolis TSAPAKIS. Bidirectional air-sea exchange and accumulation of POPs (PAHs, PCBs, OCPs and PBDEs) in the nocturnal marine boundary layer. \textit{Atmospheric Chemistry and Physics}. GOTTINGEN: European Geosciences Union, 2016, vol.~16, No~10, p.~6381-6393. ISSN~1680-7316. Available from: https://dx.doi.org/10.5194/acp-16-6381-2016.

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