In situ calibration of three passive samplers for the
monitoring of steroid hormones in wastewater

J 2016

In situ calibration of three passive samplers for the monitoring of steroid hormones in wastewater

OTOUPALÍKOVÁ, Alena, Roman PROKEŠ, Zdeněk ŠIMEK and Branislav VRANA

Basic information

Original name

In situ calibration of three passive samplers for the monitoring of steroid hormones in wastewater

Authors

OTOUPALÍKOVÁ, Alena (203 Czech Republic, belonging to the institution), Roman PROKEŠ (203 Czech Republic, belonging to the institution), Zdeněk ŠIMEK (203 Czech Republic, belonging to the institution) and Branislav VRANA (703 Slovakia, guarantor, belonging to the institution)

Edition

Talanta, AMSTERDAM, Elsevier, 2016, 0039-9140

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10406 Analytical chemistry

Country of publisher

Netherlands

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Impact factor

Impact factor: 4.162

RIV identification code

RIV/00216224:14310/16:00088653

Organization unit

Faculty of Science

DOI

http://dx.doi.org/10.1016/j.talanta.2016.08.068

UT WoS

000386989500051

Keywords in English

Water monitoring; Steroid hormones; Passive sampling; Waste water; Chemcatcher; POCIS

Abstract

V originále

In situ extraction of steroid hormones from waste water using adsorption-based integrative passive samplers represents a promising approach for their monitoring in water at ultra-trace concentrations. Three passive samplers, namely a POCIS, a Chemcatcher fitted with an Empore SDB-RPS disk, and an Empore SDB-RPS disk-based sampler with enhanced water flow, were calibrated in situ in treated municipal wastewater for the purpose of monitoring five estrogens (17-beta-estradiol, 17-alpha-estradiol, 17-alpha-ethinylestradiol, estrone and estriol) at sub ng per litre concentrations. Uptake of steroids to samplers during 14-day exposure in wastewater was compared with steroid concentrations in daily collected composite water samples. Sampling rates were obtained from a numerical solution of first order uptake kinetics equations describing the uptake of compounds into a passive sampler over time. Mass transfer of steroids in the Chemcatcher fitted with naked Empore disks was more than two times faster than in the POCIS sampler. The uptake capacity of the applied Empore disk was not sufficient for integrative uptake of all tested steroids during the entire 14-day exposure. Time-weighted average concentrations of steroids estimated at concentrations in units of ng L-1 using the in situ-calibrated samplers were within a factor of two from values obtained using composite water samples.

Links

GA13-20357S, research and development project

Name: Studium distribuce steroidních látek ve složkách pevných environmentálních matric.

Investor: Czech Science Foundation

LM2015051, research and development project

Name: Centrum pro výzkum toxických látek v prostředí (Acronym: RECETOX RI)

Investor: Ministry of Education, Youth and Sports of the CR

LO1214, research and development project

Name: Centrum pro výzkum toxických látek v prostředí (Acronym: RECETOX)

Investor: Ministry of Education, Youth and Sports of the CR

Citovat

OTOUPALÍKOVÁ, Alena, Roman PROKEŠ, Zdeněk ŠIMEK and Branislav VRANA. In situ calibration of three passive samplers for the monitoring of steroid hormones in wastewater. Talanta. AMSTERDAM: Elsevier, 2016, vol. 161, December, p. 405-412. ISSN 0039-9140. Available from: https://dx.doi.org/10.1016/j.talanta.2016.08.068.

@article{1371892,
   author = {Otoupalíková, Alena and Prokeš, Roman and Šimek, Zdeněk and Vrana, Branislav},
   article_location = {AMSTERDAM},
   article_number = {December},
   doi = {http://dx.doi.org/10.1016/j.talanta.2016.08.068},
   keywords = {Water monitoring; Steroid hormones; Passive sampling; Waste water; Chemcatcher; POCIS},
   language = {eng},
   issn = {0039-9140},
   journal = {Talanta},
   title = {In situ calibration of three passive samplers for the monitoring of steroid hormones in wastewater},
   url = {http://www.sciencedirect.com/science/article/pii/S003991401630652X},
   volume = {161},
   year = {2016}
}

TY  - JOUR
ID  - 1371892
AU  - Otoupalíková, Alena - Prokeš, Roman - Šimek, Zdeněk - Vrana, Branislav
PY  - 2016
TI  - In situ calibration of three passive samplers for the monitoring of steroid hormones in wastewater
JF  - Talanta
VL  - 161
IS  - December
SP  - 405-412
EP  - 405-412
PB  - Elsevier
SN  - 00399140
KW  - Water monitoring
KW  - Steroid hormones
KW  - Passive sampling
KW  - Waste water
KW  - Chemcatcher
KW  - POCIS
UR  - http://www.sciencedirect.com/science/article/pii/S003991401630652X
L2  - http://www.sciencedirect.com/science/article/pii/S003991401630652X
N2  - In situ extraction of steroid hormones from waste water using adsorption-based integrative passive samplers represents a promising approach for their monitoring in water at ultra-trace concentrations. Three passive samplers, namely a POCIS, a Chemcatcher fitted with an Empore SDB-RPS disk, and an Empore SDB-RPS disk-based sampler with enhanced water flow, were calibrated in situ in treated municipal wastewater for the purpose of monitoring five estrogens (17-beta-estradiol, 17-alpha-estradiol, 17-alpha-ethinylestradiol, estrone and estriol) at sub ng per litre concentrations. Uptake of steroids to samplers during 14-day exposure in wastewater was compared with steroid concentrations in daily collected composite water samples. Sampling rates were obtained from a numerical solution of first order uptake kinetics equations describing the uptake of compounds into a passive sampler over time. Mass transfer of steroids in the Chemcatcher fitted with naked Empore disks was more than two times faster than in the POCIS sampler. The uptake capacity of the applied Empore disk was not sufficient for integrative uptake of all tested steroids during the entire 14-day exposure. Time-weighted average concentrations of steroids estimated at concentrations in units of ng L-1 using the in situ-calibrated samplers were within a factor of two from values obtained using composite water samples.
ER  -

OTOUPALÍKOVÁ, Alena, Roman PROKEŠ, Zdeněk ŠIMEK and Branislav VRANA. In situ calibration of three passive samplers for the monitoring of steroid hormones in wastewater. \textit{Talanta}. AMSTERDAM: Elsevier, 2016, vol.~161, December, p.~405-412. ISSN~0039-9140. Available from: https://dx.doi.org/10.1016/j.talanta.2016.08.068.

Detailed Information on Publication Record