a 2016

Study of mineralization in geological samples by means of LIBS and neural networks

KLUS, Jakub, Pavel POŘÍZKA, David PROCHAZKA, Petr MIKYSEK, Jan NOVOTNÝ et. al.

Basic information

Original name

Study of mineralization in geological samples by means of LIBS and neural networks

Authors

KLUS, Jakub (203 Czech Republic), Pavel POŘÍZKA (203 Czech Republic), David PROCHAZKA (203 Czech Republic), Petr MIKYSEK (203 Czech Republic, belonging to the institution), Jan NOVOTNÝ (203 Czech Republic), Karel NOVOTNÝ (203 Czech Republic, guarantor, belonging to the institution) and Jozef KAISER (203 Czech Republic)

Edition

9-th International Conference on Laser-Induced Breakdown Spectroscopy - LIBS2016, 2016

Other information

Language

English

Type of outcome

Konferenční abstrakt

Field of Study

10406 Analytical chemistry

Country of publisher

France

Confidentiality degree

není předmětem státního či obchodního tajemství

RIV identification code

RIV/00216224:14310/16:00093802

Organization unit

Faculty of Science

Keywords in English

Geology; mineralization; neural networks
Změněno: 6/3/2017 10:20, doc. Mgr. Karel Novotný, Ph.D.

Abstract

V originále

This work aims on the description of possible element association within a sample of sandstone-hosted uranium ore by means of Laser-Induced Breakdown Spectroscopy (LIBS). As an element association in the interaction region and in terms of LIBS we refer to the simultaneous presence of spectral lines within a respective single spectrum. Presented results show element associations within a sandstone ore sample carrying high abundance of zirconium, uranium, niobium and hafnium. To manage this task a multivariate method was utilized, namely the self-organized maps (SOM). SOM is a type of artificial neural network, which provides dimensionality reduction based on the similarity of input data. Responses of SOM weights associated with certain elemental lines were easily discriminated as either simultaneous or isolated. Deduced association of U-Zr and isolation of Ti, Fe and Si responses is in good correlation with geological studies made on ores from the same place of origin. Finally a mineralization visualization performed in unconventional manners is shown. Instead of the creation of chemical map by rearranging the line intensities to the rectangular grid of points, a correlation of spectra with neuron responses was calculated. It is shown that map of correlation coefficients provides better insight into the problem of element associations or possible co-mineralization in general.

Links

LQ1601, research and development project
Name: CEITEC 2020 (Acronym: CEITEC2020)
Investor: Ministry of Education, Youth and Sports of the CR