Delayed phase separation in growth of organic semiconductor
blends with limited intermixing

J 2017

Delayed phase separation in growth of organic semiconductor blends with limited intermixing

DIETERLE, Johannes, Katharina BROCH, Heiko FRANK, Giuliano DUVA, Timo STORZER et. al.

Basic information

Original name

Delayed phase separation in growth of organic semiconductor blends with limited intermixing

Authors

DIETERLE, Johannes (276 Germany), Katharina BROCH (276 Germany), Heiko FRANK (276 Germany), Giuliano DUVA (380 Italy), Timo STORZER (276 Germany), Alexander HINDERHOFER (276 Germany), Jiří NOVÁK (203 Czech Republic, guarantor, belonging to the institution), Alexander GERLACH (276 Germany) and Frank SCHREIBER (276 Germany)

Edition

Physica Status Solidi Rapid Research Letters, Weinheim, Germany, WILEY-V C H VERLAG GMBH, 2017, 1862-6254

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10302 Condensed matter physics

Country of publisher

Germany

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

Full Text

Impact factor

Impact factor: 3.721

RIV identification code

RIV/00216224:14310/17:00096490

Organization unit

Faculty of Science

DOI

http://dx.doi.org/10.1002/pssr.201600428

UT WoS

000397999700011

Keywords in English

organic semiconductors; picene; pentacene; phase separation; thin films; X-ray diffraction; blends

Abstract

V originále

Binary mixed thin films of picene (C22H14, PIC) and pentacene (C22H14, PEN) consist of crystallites with a statistical occupation of the lattice sites by either PEN or PIC and unit cell parameters continuously changing with the mixing ratio. For high PIC ratios a PIC phase forms which corresponds to a limited intermixing of the two compounds. The growth behavior of these mixtures is investigated in situ and in realtime using grazing incidence X-ray diffraction. We observe a delayed phase separation in PIC-rich blends, i.e. complete intermixing in the monolayer range and the nucleation of a pure PIC-phase in addition to the intermixed phase starting from the second monolayer.

Links

LQ1601, research and development project

Name: CEITEC 2020 (Acronym: CEITEC2020)

Investor: Ministry of Education, Youth and Sports of the CR

Citovat

DIETERLE, Johannes, Katharina BROCH, Heiko FRANK, Giuliano DUVA, Timo STORZER, Alexander HINDERHOFER, Jiří NOVÁK, Alexander GERLACH and Frank SCHREIBER. Delayed phase separation in growth of organic semiconductor blends with limited intermixing. Physica Status Solidi Rapid Research Letters. Weinheim, Germany: WILEY-V C H VERLAG GMBH, 2017, vol. 11, No 3, p. "1600428-1" - "1600428-5", 5 pp. ISSN 1862-6254. Available from: https://dx.doi.org/10.1002/pssr.201600428.

@article{1378624,
   author = {Dieterle, Johannes and Broch, Katharina and Frank, Heiko and Duva, Giuliano and Storzer, Timo and Hinderhofer, Alexander and Novák, Jiří and Gerlach, Alexander and Schreiber, Frank},
   article_location = {Weinheim, Germany},
   article_number = {3},
   doi = {http://dx.doi.org/10.1002/pssr.201600428},
   keywords = {organic semiconductors; picene; pentacene; phase separation; thin films; X-ray diffraction; blends},
   language = {eng},
   issn = {1862-6254},
   journal = {Physica Status Solidi Rapid Research Letters},
   title = {Delayed phase separation in growth of organic semiconductor blends with limited intermixing},
   url = {http://onlinelibrary.wiley.com/doi/10.1002/pssr.201600428/abstract},
   volume = {11},
   year = {2017}
}

TY  - JOUR
ID  - 1378624
AU  - Dieterle, Johannes - Broch, Katharina - Frank, Heiko - Duva, Giuliano - Storzer, Timo - Hinderhofer, Alexander - Novák, Jiří - Gerlach, Alexander - Schreiber, Frank
PY  - 2017
TI  - Delayed phase separation in growth of organic semiconductor blends with limited intermixing
JF  - Physica Status Solidi Rapid Research Letters
VL  - 11
IS  - 3
SP  - "1600428-1" - "1600428-5"
EP  - "1600428-1" - "1600428-5"
PB  - WILEY-V C H VERLAG GMBH
SN  - 18626254
KW  - organic semiconductors
KW  - picene
KW  - pentacene
KW  - phase separation
KW  - thin films
KW  - X-ray diffraction
KW  - blends
UR  - http://onlinelibrary.wiley.com/doi/10.1002/pssr.201600428/abstract
L2  - http://onlinelibrary.wiley.com/doi/10.1002/pssr.201600428/abstract
N2  - Binary mixed thin films of picene (C22H14, PIC) and pentacene (C22H14, PEN) consist of crystallites with a statistical occupation of the lattice sites by either PEN or PIC and unit cell parameters continuously changing with the mixing ratio. For high PIC ratios a PIC phase forms which corresponds to a limited intermixing of the two compounds. The growth behavior of these mixtures is investigated in situ and in realtime using grazing incidence X-ray diffraction. We observe a delayed phase separation in PIC-rich blends, i.e. complete intermixing in the monolayer range and the nucleation of a pure PIC-phase in addition to the intermixed phase starting from the second monolayer.
ER  -

DIETERLE, Johannes, Katharina BROCH, Heiko FRANK, Giuliano DUVA, Timo STORZER, Alexander HINDERHOFER, Jiří NOVÁK, Alexander GERLACH and Frank SCHREIBER. Delayed phase separation in growth of organic semiconductor blends with limited intermixing. \textit{Physica Status Solidi Rapid Research Letters}. Weinheim, Germany: WILEY-V C H VERLAG GMBH, 2017, vol.~11, No~3, p.~''1600428-1'' - ''1600428-5'', 5 pp. ISSN~1862-6254. Available from: https://dx.doi.org/10.1002/pssr.201600428.

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