J 2016

Luminescent complexes of Cu-I halides with functionalized tertiary phosphines

BARTOŠ, Peter, Petr TÁBORSKÝ and Marek NEČAS

Basic information

Original name

Luminescent complexes of Cu-I halides with functionalized tertiary phosphines

Authors

BARTOŠ, Peter (703 Slovakia, belonging to the institution), Petr TÁBORSKÝ (203 Czech Republic, belonging to the institution) and Marek NEČAS (203 Czech Republic, belonging to the institution)

Edition

Phosphorus, Sulfur, and Silicon and the related elements, ABINGDON, Taylor and Francis Inc. 2016, 1042-6507

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

United Kingdom of Great Britain and Northern Ireland

Confidentiality degree

není předmětem státního či obchodního tajemství

Impact factor

Impact factor: 0.809

RIV identification code

RIV/00216224:14310/16:00094245

Organization unit

Faculty of Science

DOI

UT WoS

000373882300023

Keywords in English

Copper(I); tertiary phosphine; luminescence; cluster

Tags

Změněno: 13/3/2018 10:18, doc. Mgr. Marek Nečas, Ph.D.

Abstract

V originále

Depending on the Cu-I halide, ligand to metal ratio, and reaction conditions, complexes with various central CuX clusters can be prepared. A series of reactions of Cu-I halides with P-III containing ligands was carried out in different molar ratios in different solvents, yielding new Cu-I complexes, which were characterized by P-31 NMR and X-ray diffraction. The P-III containing ligands were based on tertiary phosphines carrying at least one organic functional group (e.g. CN, COOH) on aryl substituents. Luminescence in the complexes and its dependence on various conditions (i.e. solvent, temperature, etc.) was studied.