BARTOŠ, Peter, Petr TÁBORSKÝ and Marek NEČAS. Luminescent complexes of Cu-I halides with functionalized tertiary phosphines. Phosphorus, Sulfur, and Silicon and the related elements. ABINGDON: Taylor and Francis Inc., vol. 191, No 4, p. 645-647. ISSN 1042-6507. doi:10.1080/10426507.2015.1128926. 2016.
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Basic information
Original name Luminescent complexes of Cu-I halides with functionalized tertiary phosphines
Authors BARTOŠ, Peter (703 Slovakia, belonging to the institution), Petr TÁBORSKÝ (203 Czech Republic, belonging to the institution) and Marek NEČAS (203 Czech Republic, belonging to the institution).
Edition Phosphorus, Sulfur, and Silicon and the related elements, ABINGDON, Taylor and Francis Inc. 2016, 1042-6507.
Other information
Original language English
Type of outcome Article in a journal
Field of Study 10402 Inorganic and nuclear chemistry
Country of publisher United Kingdom of Great Britain and Northern Ireland
Confidentiality degree is not subject to a state or trade secret
Impact factor Impact factor: 0.809
RIV identification code RIV/00216224:14310/16:00094245
Organization unit Faculty of Science
Doi http://dx.doi.org/10.1080/10426507.2015.1128926
UT WoS 000373882300023
Keywords in English Copper(I); tertiary phosphine; luminescence; cluster
Tags AKR, rivok
Changed by Changed by: doc. Mgr. Marek Nečas, Ph.D., učo 18809. Changed: 13/3/2018 10:18.
Abstract
Depending on the Cu-I halide, ligand to metal ratio, and reaction conditions, complexes with various central CuX clusters can be prepared. A series of reactions of Cu-I halides with P-III containing ligands was carried out in different molar ratios in different solvents, yielding new Cu-I complexes, which were characterized by P-31 NMR and X-ray diffraction. The P-III containing ligands were based on tertiary phosphines carrying at least one organic functional group (e.g. CN, COOH) on aryl substituents. Luminescence in the complexes and its dependence on various conditions (i.e. solvent, temperature, etc.) was studied.
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