J 2017

Fluorescence measurement of atomic oxygen concentration in a dielectric barrier discharge

DVOŘÁK, Pavel, Martina MRKVIČKOVÁ, Adam OBRUSNÍK, Kratzer JAN, Dědina JIŘÍ et. al.

Basic information

Original name

Fluorescence measurement of atomic oxygen concentration in a dielectric barrier discharge

Name in Czech

Fluorescenční měření koncentrace atomárního kyslíku v dielektrickém bariérovém výboji

Authors

DVOŘÁK, Pavel (203 Czech Republic, guarantor, belonging to the institution), Martina MRKVIČKOVÁ (203 Czech Republic, belonging to the institution), Adam OBRUSNÍK (203 Czech Republic, belonging to the institution), Kratzer JAN (203 Czech Republic), Dědina JIŘÍ (203 Czech Republic) and Vojtěch PROCHÁZKA (203 Czech Republic, belonging to the institution)

Edition

Plasma Sources Science and Technology, Bristol, England, IOP PUBLISHING LTD, 2017, 0963-0252

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10305 Fluids and plasma physics

Country of publisher

United Kingdom of Great Britain and Northern Ireland

Confidentiality degree

není předmětem státního či obchodního tajemství

Impact factor

Impact factor: 3.939

RIV identification code

RIV/00216224:14310/17:00094851

Organization unit

Faculty of Science

UT WoS

000403309700002

Keywords (in Czech)

Laserem indukovaná fluorescence; TALIF; atomární kyslík; O; dielektrický bariérový výboj

Keywords in English

Laser induced fluorescence; TALIF; atomic oxygen; O; dielectric barrier discharges

Tags

Tags

International impact, Reviewed
Změněno: 3/4/2018 16:19, Ing. Nicole Zrilić

Abstract

V originále

Concentration of atomic oxygen was measured in a volume dielectric barrier discharge (DBD) ignited in mixtures of Ar + O2 (+ H2) at atmospheric pressure. Two-photon absorption laser induced fluorescence (TALIF) of atomic oxygen was used and this method was calibrated by TALIF of Xe in a mixture of argon and a trace of xenon. The calibration was performed at atmospheric pressure and it was shown that quenching by three-body collisions has negligible effect on the life time of excited Xe atoms. The concentration of atomic oxygen in the DBD was around 10^{21} m-3 and it was stable during the whole discharge period. The concentration did not depend much on the electric power delivered to the discharge provided that the power was sufficiently high so that the visible discharge filled the whole reactor volume. Both the addition of hydrogen or replacing of argon by helium led to a significant decrease of atomic oxygen concentration. The TALIF measurements of O concentration levels in the DBD plasma performed in this work are made use of e.g. in the field analytical chemistry. The results contribute to understanding the processes of analyte hydride preconcentration and subsequent atomization in the field of trace element analysis where DBD plasma atomizers are employed.

In Czech

Koncentrace atomárního kyslíku byla metodou TALIF měřena v dielektrickém bariérovém výboji iniciovaném za atmosférického tlaku ve směsích Ar + O2 (+ H2) a počítána modelem.

Links

CZ.1.05/2.1.00/03.0086, interní kód MU
Name: CEPLANT - Regionální VaV centrum pro nízkonákladové plazmové a nanotechnologické povrchové úpravy
Investor: Ministry of Education, Youth and Sports of the CR, 2.1 Regional R&D Centres
GA13-24635S, research and development project
Name: Spektroskopické studium rekombinace povrchového náboje v dielektrických bariérových výbojích
Investor: Czech Science Foundation
GA17-04329S, research and development project
Name: Atomizátory hydridů pro atomovou absorpční a atomovou fluorescenční spektrometrii - nové horizonty
Investor: Czech Science Foundation
LO1411, research and development project
Name: Rozvoj centra pro nízkonákladové plazmové a nanotechnologické povrchové úpravy (Acronym: CEPLANT plus)
Investor: Ministry of Education, Youth and Sports of the CR
7AMB14SK204, research and development project
Name: Studium nerovnovážného difúzního plazmatu generovaného ve vodních parách za atmosférického tlaku optickými a laserovými metodami (Acronym: LIFOH)
Investor: Ministry of Education, Youth and Sports of the CR