The Power of Non-Hydrolytic Sol-Gel Chemistry: A Review

J 2017

The Power of Non-Hydrolytic Sol-Gel Chemistry: A Review

STÝSKALÍK, Aleš, David ŠKODA, Craig E BARNES and Jiří PINKAS

Basic information

Original name

The Power of Non-Hydrolytic Sol-Gel Chemistry: A Review

Authors

STÝSKALÍK, Aleš (203 Czech Republic, guarantor, belonging to the institution), David ŠKODA (203 Czech Republic), Craig E BARNES (840 United States of America) and Jiří PINKAS (203 Czech Republic, belonging to the institution)

Edition

CATALYSTS, BASEL, MDPI AG, 2017, 2073-4344

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

Switzerland

Confidentiality degree

není předmětem státního či obchodního tajemství

Impact factor

Impact factor: 3.465

RIV identification code

RIV/00216224:14310/17:00098062

Organization unit

Faculty of Science

DOI

http://dx.doi.org/10.3390/catal7060168

UT WoS

000404380300002

Keywords in English

non-hydrolytic; sol-gel; non-aqueous; metal oxides; porosity

Abstract

V originále

This review is devoted to non-hydrolytic sol-gel chemistry. During the last 25 years, non-hydrolytic sol-gel (NHSG) techniques were found to be attractive and versatile methods for the preparation of oxide materials. Compared to conventional hydrolytic approaches, the NHSG route allows reaction control at the atomic scale resulting in homogeneous and well defined products. Due to these features and the ability to design specific materials, the products of NHSG reactions have been used in many fields of application. The aim of this review is to present an overview of NHSG research in recent years with an emphasis on the syntheses of mixed oxides, silicates and phosphates. The first part of the review highlights well known condensation reactions with some deeper insights into their mechanism and also presents novel condensation reactions established in NHSG chemistry in recent years. In the second section we discuss porosity control and novel compositions of selected materials. In the last part, the applications of NHSG derived materials as heterogeneous catalysts and supports, luminescent materials and electrode materials in Li-ion batteries are described.

Links

LQ1601, research and development project

Name: CEITEC 2020 (Acronym: CEITEC2020)

Investor: Ministry of Education, Youth and Sports of the CR

Citovat

STÝSKALÍK, Aleš, David ŠKODA, Craig E BARNES and Jiří PINKAS. The Power of Non-Hydrolytic Sol-Gel Chemistry: A Review. CATALYSTS. BASEL: MDPI AG, 2017, vol. 7, No 6, p. nestránkováno, 42 pp. ISSN 2073-4344. Available from: https://dx.doi.org/10.3390/catal7060168.

@article{1393658,
   author = {Stýskalík, Aleš and Škoda, David and Barnes, Craig E and Pinkas, Jiří},
   article_location = {BASEL},
   article_number = {6},
   doi = {http://dx.doi.org/10.3390/catal7060168},
   keywords = {non-hydrolytic; sol-gel; non-aqueous; metal oxides; porosity},
   language = {eng},
   issn = {2073-4344},
   journal = {CATALYSTS},
   title = {The Power of Non-Hydrolytic Sol-Gel Chemistry: A Review},
   volume = {7},
   year = {2017}
}

TY  - JOUR
ID  - 1393658
AU  - Stýskalík, Aleš - Škoda, David - Barnes, Craig E - Pinkas, Jiří
PY  - 2017
TI  - The Power of Non-Hydrolytic Sol-Gel Chemistry: A Review
JF  - CATALYSTS
VL  - 7
IS  - 6
SP  - nestránkováno
EP  - nestránkováno
PB  - MDPI AG
SN  - 20734344
KW  - non-hydrolytic
KW  - sol-gel
KW  - non-aqueous
KW  - metal oxides
KW  - porosity
N2  - This review is devoted to non-hydrolytic sol-gel chemistry. During the last 25 years, non-hydrolytic sol-gel (NHSG) techniques were found to be attractive and versatile methods for the preparation of oxide materials. Compared to conventional hydrolytic approaches, the NHSG route allows reaction control at the atomic scale resulting in homogeneous and well defined products. Due to these features and the ability to design specific materials, the products of NHSG reactions have been used in many fields of application. The aim of this review is to present an overview of NHSG research in recent years with an emphasis on the syntheses of mixed oxides, silicates and phosphates. The first part of the review highlights well known condensation reactions with some deeper insights into their mechanism and also presents novel condensation reactions established in NHSG chemistry in recent years. In the second section we discuss porosity control and novel compositions of selected materials. In the last part, the applications of NHSG derived materials as heterogeneous catalysts and supports, luminescent materials and electrode materials in Li-ion batteries are described.
ER  -

STÝSKALÍK, Aleš, David ŠKODA, Craig E BARNES and Jiří PINKAS. The Power of Non-Hydrolytic Sol-Gel Chemistry: A Review. \textit{CATALYSTS}. BASEL: MDPI AG, 2017, vol.~7, No~6, p.~nestránkováno, 42 pp. ISSN~2073-4344. Available from: https://dx.doi.org/10.3390/catal7060168.

Detailed Information on Publication Record