| TORTI, Edoardo, Václav HAVEL, Mirza Arfan YAWER, Lucie LUDVÍKOVÁ, Michal BABIAK, Petr KLÁN a Vladimír ŠINDELÁŘ. Supramolecular Storage and Controlled Photorelease of an Oxidizing Agent using a Bambusuril Macrocycle. Chemistry - A European Journal. WEINHEIM: Wiley, 2017, roč. 23, č. 66, s. 16768-16772. ISSN 0947-6539. Dostupné z: https://dx.doi.org/10.1002/chem.201704948. |
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@article{1400290,
author = {Torti, Edoardo and Havel, Václav and Yawer, Mirza Arfan and Ludvíková, Lucie and Babiak, Michal and Klán, Petr and Šindelář, Vladimír},
article_location = {WEINHEIM},
article_number = {66},
doi = {http://dx.doi.org/10.1002/chem.201704948},
keywords = {anion recognition; bambusurils; controlled release; macrocycles; self-assembly},
language = {eng},
issn = {0947-6539},
journal = {Chemistry - A European Journal},
title = {Supramolecular Storage and Controlled Photorelease of an Oxidizing Agent using a Bambusuril Macrocycle},
url = {http://onlinelibrary.wiley.com/doi/10.1002/chem.201704948/abstract},
volume = {23},
year = {2017}
}
TY - JOUR
ID - 1400290
AU - Torti, Edoardo - Havel, Václav - Yawer, Mirza Arfan - Ludvíková, Lucie - Babiak, Michal - Klán, Petr - Šindelář, Vladimír
PY - 2017
TI - Supramolecular Storage and Controlled Photorelease of an Oxidizing Agent using a Bambusuril Macrocycle
JF - Chemistry - A European Journal
VL - 23
IS - 66
SP - 16768-16772
EP - 16768-16772
PB - Wiley
SN - 09476539
KW - anion recognition
KW - bambusurils
KW - controlled release
KW - macrocycles
KW - self-assembly
UR - http://onlinelibrary.wiley.com/doi/10.1002/chem.201704948/abstract
L2 - http://onlinelibrary.wiley.com/doi/10.1002/chem.201704948/abstract
N2 - The oxidizing ability of peroxodisulfate upon complexation inside the Bambusuril macrocycle cavity is inhibited. This dianionic agent can be released on demand from its stable 1:1 complex in water (log K-a = 6.9 M-1) by addition of a more strongly bound anion, such as iodide (log K-a = 7.1 M-1), which can also be delivered in situ upon irradiation from a 4-hydroxyphenacyl iodide derivative with spatial and temporal precision. The oxidizing properties of peroxodisulfate ions liberated from the complex recover and can take part in subsequent chemical transformations.
ER -
TORTI, Edoardo, Václav HAVEL, Mirza Arfan YAWER, Lucie LUDVÍKOVÁ, Michal BABIAK, Petr KLÁN a Vladimír ŠINDELÁŘ. Supramolecular Storage and Controlled Photorelease of an Oxidizing Agent using a Bambusuril Macrocycle. \textit{Chemistry - A European Journal}. WEINHEIM: Wiley, 2017, roč.~23, č.~66, s.~16768-16772. ISSN~0947-6539. Dostupné z: https://dx.doi.org/10.1002/chem.201704948.
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