J 2017

Supramolecular Storage and Controlled Photorelease of an Oxidizing Agent using a Bambusuril Macrocycle

TORTI, Edoardo, Václav HAVEL, Mirza Arfan YAWER, Lucie LUDVÍKOVÁ, Michal BABIAK et. al.

Basic information

Original name

Supramolecular Storage and Controlled Photorelease of an Oxidizing Agent using a Bambusuril Macrocycle

Authors

TORTI, Edoardo (380 Italy, belonging to the institution), Václav HAVEL (203 Czech Republic, belonging to the institution), Mirza Arfan YAWER (586 Pakistan, belonging to the institution), Lucie LUDVÍKOVÁ (203 Czech Republic, belonging to the institution), Michal BABIAK (703 Slovakia, belonging to the institution), Petr KLÁN (203 Czech Republic, belonging to the institution) and Vladimír ŠINDELÁŘ (203 Czech Republic, guarantor, belonging to the institution)

Edition

Chemistry - A European Journal, WEINHEIM, Wiley, 2017, 0947-6539

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10404 Polymer science

Country of publisher

Germany

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

Impact factor

Impact factor: 5.160

RIV identification code

RIV/00216224:14310/17:00095282

Organization unit

Faculty of Science

DOI

UT WoS

000416549200012

Keywords in English

anion recognition; bambusurils; controlled release; macrocycles; self-assembly

Tags

Tags

International impact, Reviewed
Změněno: 12/4/2018 10:11, Ing. Nicole Zrilić

Abstract

V originále

The oxidizing ability of peroxodisulfate upon complexation inside the Bambusuril macrocycle cavity is inhibited. This dianionic agent can be released on demand from its stable 1:1 complex in water (log K-a = 6.9 M-1) by addition of a more strongly bound anion, such as iodide (log K-a = 7.1 M-1), which can also be delivered in situ upon irradiation from a 4-hydroxyphenacyl iodide derivative with spatial and temporal precision. The oxidizing properties of peroxodisulfate ions liberated from the complex recover and can take part in subsequent chemical transformations.

Links

GA13-15576S, research and development project
Name: Syntéza a supramolekulární vlastnosti bambusurilů
Investor: Czech Science Foundation
GA13-25775S, research and development project
Name: Vývoj viditelným světlem aktivovatelných skupin a fluorescenčních značek pro chemii a biologii
Investor: Czech Science Foundation
LM2015043, research and development project
Name: Česká infrastruktura pro integrativní strukturní biologii (Acronym: CIISB)
Investor: Ministry of Education, Youth and Sports of the CR
LM2015051, research and development project
Name: Centrum pro výzkum toxických látek v prostředí (Acronym: RECETOX RI)
Investor: Ministry of Education, Youth and Sports of the CR
LO1214, research and development project
Name: Centrum pro výzkum toxických látek v prostředí (Acronym: RECETOX)
Investor: Ministry of Education, Youth and Sports of the CR
LQ1601, research and development project
Name: CEITEC 2020 (Acronym: CEITEC2020)
Investor: Ministry of Education, Youth and Sports of the CR