Laser Desorption Ionization of As2Ch3 (Ch = S, Se, and Te)
Chalcogenides Using Quadrupole Ion Trap Time-of-Flight Mass
Spectrometry: A Comparative Study

J 2017

Laser Desorption Ionization of As2Ch3 (Ch = S, Se, and Te) Chalcogenides Using Quadrupole Ion Trap Time-of-Flight Mass Spectrometry: A Comparative Study

MAWALE, Ravi, Mayuri Vilas AUSEKAR, Lubomír PROKEŠ, Virginie NAZABAL, Emeline BAUDET et. al.

Basic information

Original name

Laser Desorption Ionization of As2Ch3 (Ch = S, Se, and Te) Chalcogenides Using Quadrupole Ion Trap Time-of-Flight Mass Spectrometry: A Comparative Study

Authors

MAWALE, Ravi (356 India, belonging to the institution), Mayuri Vilas AUSEKAR (356 India, belonging to the institution), Lubomír PROKEŠ (203 Czech Republic, belonging to the institution), Virginie NAZABAL (250 France), Emeline BAUDET (203 Czech Republic), Tomas HALENKOVIC (203 Czech Republic), Marek BOUSKA (203 Czech Republic), Milan ALBERTI (203 Czech Republic, belonging to the institution), Petr NEMEC (203 Czech Republic) and Josef HAVEL (203 Czech Republic, guarantor, belonging to the institution)

Edition

Journal of the American Society for Mass Spectrometry, USA, Springer New York LLC, 2017, 1044-0305

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10406 Analytical chemistry

Country of publisher

United States of America

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Impact factor

Impact factor: 2.869

RIV identification code

RIV/00216224:14310/17:00095295

Organization unit

Faculty of Science

DOI

http://dx.doi.org/10.1007/s13361-017-1785-x

UT WoS

000416567600006

Keywords in English

Chalcogenides; Structure; Laser desorption ionization; Time-of-flight mass spectrometry; Clusters

Abstract

V originále

Laser desorption ionization using time-of-flight mass spectrometer afforded with quadrupole ion trap was used to study As2Ch3 (Ch = S, Se, and Te) bulk chalcogenide materials. The main goal of the study is the identification of species present in the plasma originating from the interaction of laser pulses with solid state material. The generated clusters in both positive and negative ion mode are identified as 10 unary (Sp +/– and Asm +/– ) and 34 binary (AsmSp +/– ) species for As2S3 glass, 2 unary (Seq +/– ) and 26 binary (AsmSeq +/– ) species for As2Se3 glass, 7 unary (Ter +/– ) and 23 binary (AsmTer +/– ) species for As2Te3 material. The fragmentation of chalcogenide materials was diminished using some polymers and in this way 45 new, higher mass clusters have been detected. This novel approach opens a new possibility for laser desorption ionization mass spectrometry analysis of chalcogenides as well as other materials.

Links

ED2.1.00/03.0086, research and development project

Name: Regionální VaV centrum pro nízkonákladové plazmové a nanotechnologické povrchové úpravy

Citovat

MAWALE, Ravi, Mayuri Vilas AUSEKAR, Lubomír PROKEŠ, Virginie NAZABAL, Emeline BAUDET, Tomas HALENKOVIC, Marek BOUSKA, Milan ALBERTI, Petr NEMEC and Josef HAVEL. Laser Desorption Ionization of As2Ch3 (Ch = S, Se, and Te) Chalcogenides Using Quadrupole Ion Trap Time-of-Flight Mass Spectrometry: A Comparative Study. Journal of the American Society for Mass Spectrometry. USA: Springer New York LLC, 2017, vol. 27, No 12, p. 2569-2579. ISSN 1044-0305. Available from: https://dx.doi.org/10.1007/s13361-017-1785-x.

@article{1400772,
   author = {Mawale, Ravi and Ausekar, Mayuri Vilas and Prokeš, Lubomír and Nazabal, Virginie and Baudet, Emeline and Halenkovic, Tomas and Bouska, Marek and Alberti, Milan and Nemec, Petr and Havel, Josef},
   article_location = {USA},
   article_number = {12},
   doi = {http://dx.doi.org/10.1007/s13361-017-1785-x},
   keywords = {Chalcogenides; Structure; Laser desorption ionization; Time-of-flight mass spectrometry; Clusters},
   language = {eng},
   issn = {1044-0305},
   journal = {Journal of the American Society for Mass Spectrometry},
   title = {Laser Desorption Ionization of As2Ch3 (Ch = S, Se, and Te) Chalcogenides Using Quadrupole Ion Trap Time-of-Flight Mass Spectrometry: A Comparative Study},
   url = {https://link.springer.com/article/10.1007/s13361-017-1785-x},
   volume = {27},
   year = {2017}
}

TY  - JOUR
ID  - 1400772
AU  - Mawale, Ravi - Ausekar, Mayuri Vilas - Prokeš, Lubomír - Nazabal, Virginie - Baudet, Emeline - Halenkovic, Tomas - Bouska, Marek - Alberti, Milan - Nemec, Petr - Havel, Josef
PY  - 2017
TI  - Laser Desorption Ionization of As2Ch3 (Ch = S, Se, and Te) Chalcogenides Using Quadrupole Ion Trap Time-of-Flight Mass Spectrometry: A Comparative Study
JF  - Journal of the American Society for Mass Spectrometry
VL  - 27
IS  - 12
SP  - 2569-2579
EP  - 2569-2579
PB  - Springer New York LLC
SN  - 10440305
KW  - Chalcogenides
KW  - Structure
KW  - Laser desorption ionization
KW  - Time-of-flight mass spectrometry
KW  - Clusters
UR  - https://link.springer.com/article/10.1007/s13361-017-1785-x
L2  - https://link.springer.com/article/10.1007/s13361-017-1785-x
N2  - Laser desorption ionization using time-of-flight mass spectrometer afforded with quadrupole ion trap was used to study As2Ch3 (Ch = S, Se, and Te) bulk chalcogenide materials. The main goal of the study is the identification of species present in the plasma originating from the interaction of laser pulses with solid state material. The generated clusters in both positive and negative ion mode are identified as 10 unary (Sp +/– and Asm +/– ) and 34 binary (AsmSp +/– ) species for As2S3 glass, 2 unary (Seq +/– ) and 26 binary (AsmSeq +/– ) species for As2Se3 glass, 7 unary (Ter +/– ) and 23 binary (AsmTer +/– ) species for As2Te3 material. The fragmentation of chalcogenide materials was diminished using some polymers and in this way 45 new, higher mass clusters have been detected. This novel approach opens a new possibility for laser desorption ionization mass spectrometry analysis of chalcogenides as well as other materials.
ER  -

MAWALE, Ravi, Mayuri Vilas AUSEKAR, Lubomír PROKEŠ, Virginie NAZABAL, Emeline BAUDET, Tomas HALENKOVIC, Marek BOUSKA, Milan ALBERTI, Petr NEMEC and Josef HAVEL. Laser Desorption Ionization of As2Ch3 (Ch = S, Se, and Te) Chalcogenides Using Quadrupole Ion Trap Time-of-Flight Mass Spectrometry: A Comparative Study. \textit{Journal of the American Society for Mass Spectrometry}. USA: Springer New York LLC, 2017, vol.~27, No~12, p.~2569-2579. ISSN~1044-0305. Available from: https://dx.doi.org/10.1007/s13361-017-1785-x.

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