| HRBÁČ, Jan, Tomáš STRAŠÁK, Ladislav FEKETE, Vít LADÁNYI, Jan POKORNÝ, Jiří BULÍŘ, Miloš KRBAL, Jaroslav ŽÁDNÝ, Jan STORCH and Jan VACEK. Potential-Driven On/Off Switch Strategy for the Electrosynthesis of [7]Helicene-Derived Polymers. ChemElectroChem. WEINHEIM: Wiley-V C H VERLAG GMBH, 2017, vol. 4, No 12, p. 3047-3052. ISSN 2196-0216. Available from: https://dx.doi.org/10.1002/celc.201700441. |
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@article{1402121,
author = {Hrbáč, Jan and Strašák, Tomáš and Fekete, Ladislav and Ladányi, Vít and Pokorný, Jan and Bulíř, Jiří and Krbal, Miloš and Žádný, Jaroslav and Storch, Jan and Vacek, Jan},
article_location = {WEINHEIM},
article_number = {12},
doi = {http://dx.doi.org/10.1002/celc.201700441},
keywords = {Helicene; thiophene; electropolymerization; electrodeposition; carbon},
language = {eng},
issn = {2196-0216},
journal = {ChemElectroChem},
title = {Potential-Driven On/Off Switch Strategy for the Electrosynthesis of [7]Helicene-Derived Polymers},
volume = {4},
year = {2017}
}
TY - JOUR
ID - 1402121
AU - Hrbáč, Jan - Strašák, Tomáš - Fekete, Ladislav - Ladányi, Vít - Pokorný, Jan - Bulíř, Jiří - Krbal, Miloš - Žádný, Jaroslav - Storch, Jan - Vacek, Jan
PY - 2017
TI - Potential-Driven On/Off Switch Strategy for the Electrosynthesis of [7]Helicene-Derived Polymers
JF - ChemElectroChem
VL - 4
IS - 12
SP - 3047-3052
EP - 3047-3052
PB - Wiley-V C H VERLAG GMBH
SN - 21960216
KW - Helicene
KW - thiophene
KW - electropolymerization
KW - electrodeposition
KW - carbon
N2 - New materials bearing thiophene and helicene moieties were prepared by using a potential-driven on/off switch strategy on the surface of glassy carbon and indium tin oxide substrates. Specifically, a 3-([7]helicen-9-yl)-thiophene hybrid monomer was electrooxidized in acetonitrile by using cyclic voltammetry with anodic potential limits of +1.5 or +2.5 V, resulting in a conductive and non-conductive polymer, respectively. The electrochemical findings were supplemented by microscopy investigations, UV/Vis, fluorescence and vibrational spectroscopies, and 1H NMR spectroscopy as well as ellipsometry measurements and computational chemistry. The electrodeposited polymers could be used for the further development of materials applicable in organic electronics, optoelectronics, and sensing technologies.
ER -
HRBÁČ, Jan, Tomáš STRAŠÁK, Ladislav FEKETE, Vít LADÁNYI, Jan POKORNÝ, Jiří BULÍŘ, Miloš KRBAL, Jaroslav ŽÁDNÝ, Jan STORCH and Jan VACEK. Potential-Driven On/Off Switch Strategy for the Electrosynthesis of [7]Helicene-Derived Polymers. \textit{ChemElectroChem}. WEINHEIM: Wiley-V C H VERLAG GMBH, 2017, vol.~4, No~12, p.~3047-3052. ISSN~2196-0216. Available from: https://dx.doi.org/10.1002/celc.201700441.
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