Potential-Driven On/Off Switch Strategy for the
Electrosynthesis of [7]Helicene-Derived Polymers

J 2017

Potential-Driven On/Off Switch Strategy for the Electrosynthesis of [7]Helicene-Derived Polymers

HRBÁČ, Jan, Tomáš STRAŠÁK, Ladislav FEKETE, Vít LADÁNYI, Jan POKORNÝ et. al.

Basic information

Original name

Potential-Driven On/Off Switch Strategy for the Electrosynthesis of [7]Helicene-Derived Polymers

Authors

HRBÁČ, Jan (203 Czech Republic, belonging to the institution), Tomáš STRAŠÁK (203 Czech Republic), Ladislav FEKETE (203 Czech Republic), Vít LADÁNYI (203 Czech Republic, belonging to the institution), Jan POKORNÝ (203 Czech Republic), Jiří BULÍŘ (203 Czech Republic), Miloš KRBAL (203 Czech Republic), Jaroslav ŽÁDNÝ (203 Czech Republic), Jan STORCH (203 Czech Republic) and Jan VACEK (203 Czech Republic)

Edition

ChemElectroChem, WEINHEIM, Wiley-V C H VERLAG GMBH, 2017, 2196-0216

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10405 Electrochemistry

Country of publisher

Germany

Confidentiality degree

není předmětem státního či obchodního tajemství

Impact factor

Impact factor: 4.446

RIV identification code

RIV/00216224:14310/17:00099179

Organization unit

Faculty of Science

DOI

http://dx.doi.org/10.1002/celc.201700441

UT WoS

000419269000004

Keywords in English

Helicene; thiophene; electropolymerization; electrodeposition; carbon

Abstract

V originále

New materials bearing thiophene and helicene moieties were prepared by using a potential-driven on/off switch strategy on the surface of glassy carbon and indium tin oxide substrates. Specifically, a 3-([7]helicen-9-yl)-thiophene hybrid monomer was electrooxidized in acetonitrile by using cyclic voltammetry with anodic potential limits of +1.5 or +2.5 V, resulting in a conductive and non-conductive polymer, respectively. The electrochemical findings were supplemented by microscopy investigations, UV/Vis, fluorescence and vibrational spectroscopies, and 1H NMR spectroscopy as well as ellipsometry measurements and computational chemistry. The electrodeposited polymers could be used for the further development of materials applicable in organic electronics, optoelectronics, and sensing technologies.

Links

LD15058, research and development project

Name: Příprava substrátů pro povrchově zesílenou Ramanovu spektroskopii pomocí elektrochemických, elektroforetických a jiskrový výboj využívajících technik. (Acronym: ELE-SERS)

Investor: Ministry of Education, Youth and Sports of the CR

Citovat

HRBÁČ, Jan, Tomáš STRAŠÁK, Ladislav FEKETE, Vít LADÁNYI, Jan POKORNÝ, Jiří BULÍŘ, Miloš KRBAL, Jaroslav ŽÁDNÝ, Jan STORCH and Jan VACEK. Potential-Driven On/Off Switch Strategy for the Electrosynthesis of [7]Helicene-Derived Polymers. ChemElectroChem. WEINHEIM: Wiley-V C H VERLAG GMBH, 2017, vol. 4, No 12, p. 3047-3052. ISSN 2196-0216. Available from: https://dx.doi.org/10.1002/celc.201700441.

@article{1402121,
   author = {Hrbáč, Jan and Strašák, Tomáš and Fekete, Ladislav and Ladányi, Vít and Pokorný, Jan and Bulíř, Jiří and Krbal, Miloš and Žádný, Jaroslav and Storch, Jan and Vacek, Jan},
   article_location = {WEINHEIM},
   article_number = {12},
   doi = {http://dx.doi.org/10.1002/celc.201700441},
   keywords = {Helicene; thiophene; electropolymerization; electrodeposition; carbon},
   language = {eng},
   issn = {2196-0216},
   journal = {ChemElectroChem},
   title = {Potential-Driven On/Off Switch Strategy for the Electrosynthesis of [7]Helicene-Derived Polymers},
   volume = {4},
   year = {2017}
}

TY  - JOUR
ID  - 1402121
AU  - Hrbáč, Jan - Strašák, Tomáš - Fekete, Ladislav - Ladányi, Vít - Pokorný, Jan - Bulíř, Jiří - Krbal, Miloš - Žádný, Jaroslav - Storch, Jan - Vacek, Jan
PY  - 2017
TI  - Potential-Driven On/Off Switch Strategy for the Electrosynthesis of [7]Helicene-Derived Polymers
JF  - ChemElectroChem
VL  - 4
IS  - 12
SP  - 3047-3052
EP  - 3047-3052
PB  - Wiley-V C H VERLAG GMBH
SN  - 21960216
KW  - Helicene
KW  - thiophene
KW  - electropolymerization
KW  - electrodeposition
KW  - carbon
N2  - New materials bearing thiophene and helicene moieties were prepared by using a potential-driven on/off switch strategy on the surface of glassy carbon and indium tin oxide substrates. Specifically, a 3-([7]helicen-9-yl)-thiophene hybrid monomer was electrooxidized in acetonitrile by using cyclic voltammetry with anodic potential limits of +1.5 or +2.5 V, resulting in a conductive and non-conductive polymer, respectively. The electrochemical findings were supplemented by microscopy investigations, UV/Vis, fluorescence and vibrational spectroscopies, and 1H NMR spectroscopy as well as ellipsometry measurements and computational chemistry. The electrodeposited polymers could be used for the further development of materials applicable in organic electronics, optoelectronics, and sensing technologies.
ER  -

HRBÁČ, Jan, Tomáš STRAŠÁK, Ladislav FEKETE, Vít LADÁNYI, Jan POKORNÝ, Jiří BULÍŘ, Miloš KRBAL, Jaroslav ŽÁDNÝ, Jan STORCH and Jan VACEK. Potential-Driven On/Off Switch Strategy for the Electrosynthesis of [7]Helicene-Derived Polymers. \textit{ChemElectroChem}. WEINHEIM: Wiley-V C H VERLAG GMBH, 2017, vol.~4, No~12, p.~3047-3052. ISSN~2196-0216. Available from: https://dx.doi.org/10.1002/celc.201700441.

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