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@article{1408407, author = {Melymuk, Lisa Emily and BohlinandNizzetto, Pernilla and Prokeš, Roman and Kukučka, Petr and Přibylová, Petra and Vojta, Šimon and Kohoutek, Jiří and Lammel, Gerhard and Klánová, Jana}, article_location = {OXFORD}, article_number = {October}, doi = {http://dx.doi.org/10.1016/j.atmosenv.2017.08.038}, keywords = {Active air sampling; Passive air sampling; Degradation; SVOCs; Sampling artifacts}, language = {eng}, issn = {1352-2310}, journal = {Atmospheric Environment}, title = {Uncertainties in monitoring of SVOCs in air caused by within-sampler degradation during active and passive air sampling}, url = {https://www.sciencedirect.com/science/article/pii/S1352231017305514?via%3Dihub}, volume = {167}, year = {2017} }
TY - JOUR ID - 1408407 AU - Melymuk, Lisa Emily - Bohlin-Nizzetto, Pernilla - Prokeš, Roman - Kukučka, Petr - Přibylová, Petra - Vojta, Šimon - Kohoutek, Jiří - Lammel, Gerhard - Klánová, Jana PY - 2017 TI - Uncertainties in monitoring of SVOCs in air caused by within-sampler degradation during active and passive air sampling JF - Atmospheric Environment VL - 167 IS - October SP - 553-565 EP - 553-565 PB - PERGAMON-ELSEVIER SCIENCE SN - 13522310 KW - Active air sampling KW - Passive air sampling KW - Degradation KW - SVOCs KW - Sampling artifacts UR - https://www.sciencedirect.com/science/article/pii/S1352231017305514?via%3Dihub L2 - https://www.sciencedirect.com/science/article/pii/S1352231017305514?via%3Dihub N2 - Degradation of semivolatile organic compounds (SVOCs) occurs naturally in ambient air due to reactions with reactive trace gases (e.g., ozone, NO.). During air sampling there is also the possibility for degradation of SVOCs within the air sampler, leading to underestimates of ambient air concentrations. We investigated the possibility of this sampling artifact in commonly used active and passive air samplers for seven classes of SVOCs, including persistent organic pollutants (POPs) typically covered by air monitoring programs, as well as SVOCs of emerging concern. Two active air samplers were used, one equipped with an ozone denuder and one without, to compare relative differences in mass of collected compounds. Two sets of passive samplers were also deployed to determine the influence of degradation during longer deployment times in passive sampling. In active air samplers, comparison of the two sampling configurations suggested degradation of particle-bound polycyclic aromatic hydrocarbons (PAHs), with concentrations up to 2x higher in the denuder-equipped sampler, while halogenated POPs did not have clear evidence of degradation. In contrast, more polar, reactive compounds (e.g., organophosphate esters and current use pesticides) had evidence of losses in the sampler with denuder. This may be caused by the denuder itself, suggesting sampling bias for these compounds can be created when typical air sampling apparatuses are adapted to limit degradation. Passive air samplers recorded up to 4x higher concentrations when deployed for shorter consecutive sampling periods, suggesting that within-sampler degradation may also be relevant in passive air monitoring programs. ER -
MELYMUK, Lisa Emily, Pernilla BOHLIN-NIZZETTO, Roman PROKEŠ, Petr KUKUČKA, Petra PŘIBYLOVÁ, Šimon VOJTA, Jiří KOHOUTEK, Gerhard LAMMEL and Jana KLÁNOVÁ. Uncertainties in monitoring of SVOCs in air caused by within-sampler degradation during active and passive air sampling. \textit{Atmospheric Environment}. OXFORD: PERGAMON-ELSEVIER SCIENCE, 2017, vol.~167, October, p.~553-565. ISSN~1352-2310. Available from: https://dx.doi.org/10.1016/j.atmosenv.2017.08.038.
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