J 2017

Neoproterozoic amorphous "ekanite" (Ca2Th0.9U0.1Si8O20) from Okkampitiya, Sri Lanka: A metamict gemstone with excellent lead-retention performance

NASDALA, Lutz, Fernando CORFU, Doris BLAIMAUER, Chutimun CHANMUANG, Katja RUSCHEL et. al.

Basic information

Original name

Neoproterozoic amorphous "ekanite" (Ca2Th0.9U0.1Si8O20) from Okkampitiya, Sri Lanka: A metamict gemstone with excellent lead-retention performance

Authors

NASDALA, Lutz (276 Germany), Fernando CORFU (756 Switzerland), Doris BLAIMAUER (40 Austria), Chutimun CHANMUANG (40 Austria), Katja RUSCHEL (40 Austria), Radek ŠKODA (203 Czech Republic, guarantor, belonging to the institution), Manfred WILDNER (40 Austria), Richard WIRTH (276 Germany), Manuela ZEUG (40 Austria) and E. Gamini ZOYSA (144 Sri Lanka)

Edition

Geology, BOULDER, Geological Society of America, 2017, 0091-7613

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10504 Mineralogy

Country of publisher

United States of America

Confidentiality degree

není předmětem státního či obchodního tajemství

Impact factor

Impact factor: 5.073

RIV identification code

RIV/00216224:14310/17:00100314

Organization unit

Faculty of Science

UT WoS

000411705800019

Keywords in English

PB ZIRCON AGES; RADIATION-DAMAGE; ALTERED ZIRCON; GEOCHRONOLOGY; DISSOLUTION; METAMORPHISM; MICROPROBE; ACCURACY; URANIUM; SYSTEMS

Tags

Tags

International impact, Reviewed
Změněno: 9/4/2018 15:44, Ing. Nicole Zrilić

Abstract

V originále

A rare gemstone form of "ekanite" from Okkampitiya, eastern Sri Lanka, has a chemical composition of Ca2Th0.9U0.1Si8O20, corresponding to that of the tetragonal mineral ekanite. The Okkampitiya material, however, has undergone amorphization and is found in a fully metamict state, which is ascribed to the long-term accumulation of high levels of self-irradiation damage (1.38 x 10(20) alpha decay events per gram). The "ekanite" nevertheless does not show any post-growth chemical alteration, and the radiogenic Pb has been retained. The Okkampitiya "ekanite" yielded a Neoproterozoic Pb-207/Pb-206 age of 562.1 +/- 0.8 Ma (uncertainty quoted at the 95% confidence level) that is concordant within the uncertainties of decay constants. The remarkable Pb-retention performance of "ekanite" contradicts the common hypothesis that metamictization in minerals results in U-Pb discordance. The exceptional chemical durability of the heavily radiation-damaged geological material described here has also implications for materials-science research. High radiation resistance, a key criterion in the search for advanced nuclear waste forms, may not be a prerequisite for high aqueous durability of a solid.

Links

MUNI/A/1653/2016, interní kód MU
Name: Geologické, geodynamické a environmentální procesy při východním okraji Českého masívu (Acronym: Geodyn)
Investor: Masaryk University, Category A