Currently and recently used pesticides in Central European
arable soils

J 2018

Currently and recently used pesticides in Central European arable soils

HVĚZDOVÁ, Martina, Petra KOSUBOVÁ, Monika KOSIKOVA, Kerstin BRANDSTÄTTER-SCHERR, Zdeněk ŠIMEK et. al.

Basic information

Original name

Currently and recently used pesticides in Central European arable soils

Authors

HVĚZDOVÁ, Martina (203 Czech Republic, belonging to the institution), Petra KOSUBOVÁ (203 Czech Republic), Monika KOSIKOVA (203 Czech Republic), Kerstin BRANDSTÄTTER-SCHERR (40 Austria), Zdeněk ŠIMEK (203 Czech Republic, belonging to the institution), Lukas BRODSKY (203 Czech Republic), Marek ŠUDOMA (203 Czech Republic, belonging to the institution), Lucia ŠKULCOVÁ (703 Slovakia, belonging to the institution), Milan SÁŇKA (203 Czech Republic, belonging to the institution), Markéta SVOBODOVÁ (203 Czech Republic, belonging to the institution), Lucia KRKOŠKOVÁ (203 Czech Republic, belonging to the institution), Jana VAŠÍČKOVÁ (203 Czech Republic, belonging to the institution), Natália NEUWIRTHOVÁ (703 Slovakia, belonging to the institution), Lucie BIELSKÁ (203 Czech Republic, belonging to the institution) and Jakub HOFMAN (203 Czech Republic, guarantor, belonging to the institution)

Edition

Science of the Total Environment, AMSTERDAM, Elsevier, 2018, 0048-9697

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10511 Environmental sciences

Country of publisher

Netherlands

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Impact factor

Impact factor: 5.589

RIV identification code

RIV/00216224:14310/18:00100965

Organization unit

Faculty of Science

DOI

http://dx.doi.org/10.1016/j.scitotenv.2017.09.049

UT WoS

000414160500038

Keywords in English

Arable soil monitoring; Multi-residue pesticide analysis; Currently used pesticides; Pesticide transformation products; Triazine herbicides; Conazole fungicides

Abstract

V originále

Although large amounts of pesticides are used annually and amajority enters the soil to formshort-or long-term residues, extensive soil surveys for currently used pesticides (CUPs) are scarce. To determine the status of CUPs' occurrence in arable land in Central Europe, 51 CUPs and 9 transformation products (TPs) were analysed in 75 arable soils in the Czech Republic (CR) several months after the last pesticide application. Moreover, two banned triazines (simazine and atrazine) and their TPs were analysed because of their frequent detection in CR waters. Multi-residue pesticide analysis on LC-MS/MS after soil QuEChERS extraction was used. The soils contained multiple pesticide residues frequently (e.g. 51% soils with >= 5 pesticides). The levels were also noticeable (e.g. 36% soils with >= 3 pesticides exceeding the threshold of 0.01 mg/kg). After triazine herbicides (89% soils), conazole fungicides showed the second most frequent occurrence (73% soils) and also high levels (53% soils with total conazoles above 0.01 mg/kg). Frequent occurrence was found also for chloroacetanilide TPs (25% of soils), fenpropidin (20%) and diflufenican (17%). With the exception of triazines' negative correlation to soil pH, no clear relationships were found between pesticide occurrence and soil properties. Association of simazine TPs with terbuthylazine and its target crops proved the frequent residues of this banned compound originate from terbuthylazine impurities. In contrast, frequent atrazine-2-hydroxy residue is probably a legacy of high atrazine usage in the past. The occurrence and levels of compounds were closely associated with their solubility, hydrophobicity and half-life. The results showed links to CR water-monitoring findings. This study represents the first extensive survey of multiple pesticide residues in Central European arable soils, including an insight into their relationships to site and pesticide properties.

Links

GA15-20065S, research and development project

Name: Osud a biodostupnost v současnosti používaných a nových pesticidů v zemědělsky využívaných fluvizemích - vliv vlastností půd a pesticidů

Investor: Czech Science Foundation

LM2015051, research and development project

Name: Centrum pro výzkum toxických látek v prostředí (Acronym: RECETOX RI)

Investor: Ministry of Education, Youth and Sports of the CR

LO1214, research and development project

Name: Centrum pro výzkum toxických látek v prostředí (Acronym: RECETOX)

Investor: Ministry of Education, Youth and Sports of the CR

Citovat

HVĚZDOVÁ, Martina, Petra KOSUBOVÁ, Monika KOSIKOVA, Kerstin BRANDSTÄTTER-SCHERR, Zdeněk ŠIMEK, Lukas BRODSKY, Marek ŠUDOMA, Lucia ŠKULCOVÁ, Milan SÁŇKA, Markéta SVOBODOVÁ, Lucia KRKOŠKOVÁ, Jana VAŠÍČKOVÁ, Natália NEUWIRTHOVÁ, Lucie BIELSKÁ and Jakub HOFMAN. Currently and recently used pesticides in Central European arable soils. Science of the Total Environment. AMSTERDAM: Elsevier, 2018, vol. 613, February, p. 361-370. ISSN 0048-9697. Available from: https://dx.doi.org/10.1016/j.scitotenv.2017.09.049.

@article{1419092,
   author = {Hvězdová, Martina and Kosubová, Petra and Kosikova, Monika and BrandstätterandScherr, Kerstin and Šimek, Zdeněk and Brodsky, Lukas and Šudoma, Marek and Škulcová, Lucia and Sáňka, Milan and Svobodová, Markéta and Krkošková, Lucia and Vašíčková, Jana and Neuwirthová, Natália and Bielská, Lucie and Hofman, Jakub},
   article_location = {AMSTERDAM},
   article_number = {February},
   doi = {http://dx.doi.org/10.1016/j.scitotenv.2017.09.049},
   keywords = {Arable soil monitoring; Multi-residue pesticide analysis; Currently used pesticides; Pesticide transformation products; Triazine herbicides; Conazole fungicides},
   language = {eng},
   issn = {0048-9697},
   journal = {Science of the Total Environment},
   title = {Currently and recently used pesticides in Central European arable soils},
   url = {https://www.sciencedirect.com/science/article/pii/S0048969717323926?via%3Dihub},
   volume = {613},
   year = {2018}
}

TY  - JOUR
ID  - 1419092
AU  - Hvězdová, Martina - Kosubová, Petra - Kosikova, Monika - Brandstätter-Scherr, Kerstin - Šimek, Zdeněk - Brodsky, Lukas - Šudoma, Marek - Škulcová, Lucia - Sáňka, Milan - Svobodová, Markéta - Krkošková, Lucia - Vašíčková, Jana - Neuwirthová, Natália - Bielská, Lucie - Hofman, Jakub
PY  - 2018
TI  - Currently and recently used pesticides in Central European arable soils
JF  - Science of the Total Environment
VL  - 613
IS  - February
SP  - 361-370
EP  - 361-370
PB  - Elsevier
SN  - 00489697
KW  - Arable soil monitoring
KW  - Multi-residue pesticide analysis
KW  - Currently used pesticides
KW  - Pesticide transformation products
KW  - Triazine herbicides
KW  - Conazole fungicides
UR  - https://www.sciencedirect.com/science/article/pii/S0048969717323926?via%3Dihub
L2  - https://www.sciencedirect.com/science/article/pii/S0048969717323926?via%3Dihub
N2  - Although large amounts of pesticides are used annually and amajority enters the soil to formshort-or long-term residues, extensive soil surveys for currently used pesticides (CUPs) are scarce. To determine the status of CUPs' occurrence in arable land in Central Europe, 51 CUPs and 9 transformation products (TPs) were analysed in 75 arable soils in the Czech Republic (CR) several months after the last pesticide application. Moreover, two banned triazines (simazine and atrazine) and their TPs were analysed because of their frequent detection in CR waters. Multi-residue pesticide analysis on LC-MS/MS after soil QuEChERS extraction was used. The soils contained multiple pesticide residues frequently (e.g. 51% soils with >= 5 pesticides). The levels were also noticeable (e.g. 36% soils with >= 3 pesticides exceeding the threshold of 0.01 mg/kg). After triazine herbicides (89% soils), conazole fungicides showed the second most frequent occurrence (73% soils) and also high levels (53% soils with total conazoles above 0.01 mg/kg). Frequent occurrence was found also for chloroacetanilide TPs (25% of soils), fenpropidin (20%) and diflufenican (17%). With the exception of triazines' negative correlation to soil pH, no clear relationships were found between pesticide occurrence and soil properties. Association of simazine TPs with terbuthylazine and its target crops proved the frequent residues of this banned compound originate from terbuthylazine impurities. In contrast, frequent atrazine-2-hydroxy residue is probably a legacy of high atrazine usage in the past. The occurrence and levels of compounds were closely associated with their solubility, hydrophobicity and half-life. The results showed links to CR water-monitoring findings. This study represents the first extensive survey of multiple pesticide residues in Central European arable soils, including an insight into their relationships to site and pesticide properties.
ER  -

HVĚZDOVÁ, Martina, Petra KOSUBOVÁ, Monika KOSIKOVA, Kerstin BRANDSTÄTTER-SCHERR, Zdeněk ŠIMEK, Lukas BRODSKY, Marek ŠUDOMA, Lucia ŠKULCOVÁ, Milan SÁŇKA, Markéta SVOBODOVÁ, Lucia KRKOŠKOVÁ, Jana VAŠÍČKOVÁ, Natália NEUWIRTHOVÁ, Lucie BIELSKÁ and Jakub HOFMAN. Currently and recently used pesticides in Central European arable soils. \textit{Science of the Total Environment}. AMSTERDAM: Elsevier, 2018, vol.~613, February, p.~361-370. ISSN~0048-9697. Available from: https://dx.doi.org/10.1016/j.scitotenv.2017.09.049.

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