YAWER, Mirza Arfan, Kristína SLEZIAKOVÁ, Lukáš PAVLOVEC and Vladimír ŠINDELÁŘ. Bambusurils Bearing Nitro Groups and Their Further Modifications. European Journal of Organic Chemistry. Weinheim: WILEY-VCH, 2018, Neuveden, No 1, p. 41-47. ISSN 1434-193X. Available from: https://dx.doi.org/10.1002/ejoc.201701329.
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Basic information
Original name Bambusurils Bearing Nitro Groups and Their Further Modifications
Authors YAWER, Mirza Arfan (586 Pakistan, belonging to the institution), Kristína SLEZIAKOVÁ (703 Slovakia, belonging to the institution), Lukáš PAVLOVEC (203 Czech Republic, belonging to the institution) and Vladimír ŠINDELÁŘ (203 Czech Republic, guarantor, belonging to the institution).
Edition European Journal of Organic Chemistry, Weinheim, WILEY-VCH, 2018, 1434-193X.
Other information
Original language English
Type of outcome Article in a journal
Field of Study 10401 Organic chemistry
Country of publisher Germany
Confidentiality degree is not subject to a state or trade secret
WWW URL
Impact factor Impact factor: 3.029
RIV identification code RIV/00216224:14310/18:00100977
Organization unit Faculty of Science
Doi http://dx.doi.org/10.1002/ejoc.201701329
UT WoS 000419707900005
Keywords in English Macrocycles; Bambusurils; Template synthesis; Receptors; Glycolurils
Tags International impact, Reviewed
Changed by Changed by: Mgr. Michaela Hylsová, Ph.D., učo 211937. Changed: 2/6/2018 12:16.
Abstract
Bambusurils are recently developed neutral anion receptors that show a high affinity towards many inorganic anions, not only in organic solvents but also in water. However, the number of water-soluble bambusurils and also those bearing functional groups is very limited. In this paper we report the synthesis of four- and six-membered bambusurils containing eight and twelve nitro groups. All the nitro groups on the bambusuril portals could be transformed into amino functions, which provided the macrocycles with water solubility and allowed their further modification. For example, we have demonstrated the conversion of amino groups on the bambusurils into the corresponding urea-functionalized bambusuril derivatives. We also report the first example of a bambusuril bearing only two functional groups, which was prepared by the condensation of two different glycolurils.
Links
GA13-15576S, research and development projectName: Syntéza a supramolekulární vlastnosti bambusurilů
Investor: Czech Science Foundation
LM2015043, research and development projectName: Česká infrastruktura pro integrativní strukturní biologii (Acronym: CIISB)
Investor: Ministry of Education, Youth and Sports of the CR
LM2015051, research and development projectName: Centrum pro výzkum toxických látek v prostředí (Acronym: RECETOX RI)
Investor: Ministry of Education, Youth and Sports of the CR
LO1214, research and development projectName: Centrum pro výzkum toxických látek v prostředí (Acronym: RECETOX)
Investor: Ministry of Education, Youth and Sports of the CR
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