| VOHRADSKÁ, Nikoleta, Esther Maria MARQUEZ SANCHEZ - CARNERERO, Tomáš PASTIERIK, Ctibor MAZAL and Petr KLÁN. Controlled photorelease of alkynoic acids and their decarboxylative deprotection for copper-catalyzed azide/alkyne cycloaddition. Chemical communications. Cambridge: Royal Society of Chemistry, 2018, vol. 54, No 44, p. 5558-5561. ISSN 1359-7345. Available from: https://dx.doi.org/10.1039/c8cc03341b. |
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@article{1488114,
author = {Vohradská, Nikoleta and Marquez Sanchez and Carnerero, Esther Maria and Pastierik, Tomáš and Mazal, Ctibor and Klán, Petr},
article_location = {Cambridge},
article_number = {44},
doi = {http://dx.doi.org/10.1039/c8cc03341b},
keywords = {PHOTOREMOVABLE PROTECTING GROUPS; ONE-POT SYNTHESIS; COUPLING REACTIONS; BORON DIPYRROMETHENE; CARBOXYLIC-ACIDS; CLICK CHEMISTRY; PROPIOLIC ACID; ARYL IODIDES; GREEN LIGHT},
language = {eng},
issn = {1359-7345},
journal = {Chemical communications},
title = {Controlled photorelease of alkynoic acids and their decarboxylative deprotection for copper-catalyzed azide/alkyne cycloaddition},
url = {https://pubs.rsc.org/en/Content/ArticleLanding/2018/CC/C8CC03341B#!divAbstract},
volume = {54},
year = {2018}
}
TY - JOUR
ID - 1488114
AU - Vohradská, Nikoleta - Marquez Sanchez - Carnerero, Esther Maria - Pastierik, Tomáš - Mazal, Ctibor - Klán, Petr
PY - 2018
TI - Controlled photorelease of alkynoic acids and their decarboxylative deprotection for copper-catalyzed azide/alkyne cycloaddition
JF - Chemical communications
VL - 54
IS - 44
SP - 5558-5561
EP - 5558-5561
PB - Royal Society of Chemistry
SN - 13597345
KW - PHOTOREMOVABLE PROTECTING GROUPS
KW - ONE-POT SYNTHESIS
KW - COUPLING REACTIONS
KW - BORON DIPYRROMETHENE
KW - CARBOXYLIC-ACIDS
KW - CLICK CHEMISTRY
KW - PROPIOLIC ACID
KW - ARYL IODIDES
KW - GREEN LIGHT
UR - https://pubs.rsc.org/en/Content/ArticleLanding/2018/CC/C8CC03341B#!divAbstract
L2 - https://pubs.rsc.org/en/Content/ArticleLanding/2018/CC/C8CC03341B#!divAbstract
N2 - A controlled photorelease of alkynoic acids from the meso-methyl BODIPY photoremovable protecting group facilitates their subsequent efficient decarboxylation to give terminal alkynes for a Cu-I-catalyzed azide/ alkyne cycloaddition. The quantum efficiencies of the photochemical step and the kinetics of the click reaction step are reported.
ER -
VOHRADSKÁ, Nikoleta, Esther Maria MARQUEZ SANCHEZ - CARNERERO, Tomáš PASTIERIK, Ctibor MAZAL and Petr KLÁN. Controlled photorelease of alkynoic acids and their decarboxylative deprotection for copper-catalyzed azide/alkyne cycloaddition. \textit{Chemical communications}. Cambridge: Royal Society of Chemistry, 2018, vol.~54, No~44, p.~5558-5561. ISSN~1359-7345. Available from: https://dx.doi.org/10.1039/c8cc03341b.
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