Distinct Speciation of Naphthalene Vapor Deposited on Ice
Surfaces at 253 or 77 K: Formation of Submicrometer-Sized
Crystals or an Amorphous Layer

J 2018

Distinct Speciation of Naphthalene Vapor Deposited on Ice Surfaces at 253 or 77 K: Formation of Submicrometer-Sized Crystals or an Amorphous Layer

ONDRUŠKOVÁ, Gabriela, Ján KRAUSKO, Josef N. STERN, Astrid HAUPTMANN, Thomas LOERTING et. al.

Basic information

Original name

Distinct Speciation of Naphthalene Vapor Deposited on Ice Surfaces at 253 or 77 K: Formation of Submicrometer-Sized Crystals or an Amorphous Layer

Authors

ONDRUŠKOVÁ, Gabriela (703 Slovakia, belonging to the institution), Ján KRAUSKO (703 Slovakia, belonging to the institution), Josef N. STERN (40 Austria), Astrid HAUPTMANN (40 Austria), Thomas LOERTING (40 Austria) and Dominik HEGER (203 Czech Republic, guarantor, belonging to the institution)

Edition

Journal of Physical Chemistry C, Washington D.C. American Chemical Society, 2018, 1932-7447

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10400 1.4 Chemical sciences

Country of publisher

United States of America

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Impact factor

Impact factor: 4.309

RIV identification code

RIV/00216224:14310/18:00101696

Organization unit

Faculty of Science

DOI

http://dx.doi.org/10.1021/acs.jpcc.8b03972

UT WoS

000435020300039

Keywords in English

POLYCYCLIC AROMATIC-HYDROCARBONS; EXPERIMENTAL-COMPUTATIONAL APPROACH; ACETIC-ACID; NITRIC-ACID; SPECTROSCOPIC PROPERTIES; HYDROGEN-CHLORIDE; ATMOSPHERIC CHEMISTRY; FLUORESCENCE-SPECTRA; PHYSICAL ADSORPTION; ORGANIC-MOLECULES

Abstract

V originále

Naphthalene was deposited from the vapor phase on ice surfaces at 77 or 253 K to yield strongly distinct behavior, forming either an amorphous glass layer or submicrometer-sized crystals, respectively. The results stand upon optical emission spectroscopy combined with differential scanning calorimetry and X-ray analysis. The amorphous layer of naphthalene on the ice behaves in the same manner as on an inert metallic support: it starts to relax at 105 K and crystallizes at 185 K. The formed microcrystals exhibit distinct absorption behavior on the ice surface and are thus expected to have a photokinetic profile varying from freeze-concentrated solutions. The observations bring implications toward environmental and extraterrestrial ice sciences.

Links

CZ.02.1.01/0.0/0.0/16_013/0001761, interní kód MU

Name: RECETOX RI - OP VVV (Acronym: RECETOX RI)

Investor: Ministry of Education, Youth and Sports of the CR, Priority axis 1: Strengthening capacities for high-quality research

GA15-12386S, research and development project

Name: Dynamika a (foto)chemie polutantů na rozhraních led/vzduch a voda/vzduch z experimentu i teorie

Investor: Czech Science Foundation

LM2015051, research and development project

Name: Centrum pro výzkum toxických látek v prostředí (Acronym: RECETOX RI)

Investor: Ministry of Education, Youth and Sports of the CR

Citovat

ONDRUŠKOVÁ, Gabriela, Ján KRAUSKO, Josef N. STERN, Astrid HAUPTMANN, Thomas LOERTING and Dominik HEGER. Distinct Speciation of Naphthalene Vapor Deposited on Ice Surfaces at 253 or 77 K: Formation of Submicrometer-Sized Crystals or an Amorphous Layer. Journal of Physical Chemistry C. Washington D.C.: American Chemical Society, 2018, vol. 122, No 22, p. 11945-11953. ISSN 1932-7447. Available from: https://dx.doi.org/10.1021/acs.jpcc.8b03972.

@article{1495400,
   author = {Ondrušková, Gabriela and Krausko, Ján and Stern, Josef N. and Hauptmann, Astrid and Loerting, Thomas and Heger, Dominik},
   article_location = {Washington D.C.},
   article_number = {22},
   doi = {http://dx.doi.org/10.1021/acs.jpcc.8b03972},
   keywords = {POLYCYCLIC AROMATIC-HYDROCARBONS; EXPERIMENTAL-COMPUTATIONAL APPROACH; ACETIC-ACID; NITRIC-ACID; SPECTROSCOPIC PROPERTIES; HYDROGEN-CHLORIDE; ATMOSPHERIC CHEMISTRY; FLUORESCENCE-SPECTRA; PHYSICAL ADSORPTION; ORGANIC-MOLECULES},
   language = {eng},
   issn = {1932-7447},
   journal = {Journal of Physical Chemistry C},
   title = {Distinct Speciation of Naphthalene Vapor Deposited on Ice Surfaces at 253 or 77 K: Formation of Submicrometer-Sized Crystals or an Amorphous Layer},
   url = {https://pubs.acs.org/doi/10.1021/acs.jpcc.8b03972},
   volume = {122},
   year = {2018}
}

TY  - JOUR
ID  - 1495400
AU  - Ondrušková, Gabriela - Krausko, Ján - Stern, Josef N. - Hauptmann, Astrid - Loerting, Thomas - Heger, Dominik
PY  - 2018
TI  - Distinct Speciation of Naphthalene Vapor Deposited on Ice Surfaces at 253 or 77 K: Formation of Submicrometer-Sized Crystals or an Amorphous Layer
JF  - Journal of Physical Chemistry C
VL  - 122
IS  - 22
SP  - 11945-11953
EP  - 11945-11953
PB  - American Chemical Society
SN  - 19327447
KW  - POLYCYCLIC AROMATIC-HYDROCARBONS
KW  - EXPERIMENTAL-COMPUTATIONAL APPROACH
KW  - ACETIC-ACID
KW  - NITRIC-ACID
KW  - SPECTROSCOPIC PROPERTIES
KW  - HYDROGEN-CHLORIDE
KW  - ATMOSPHERIC CHEMISTRY
KW  - FLUORESCENCE-SPECTRA
KW  - PHYSICAL ADSORPTION
KW  - ORGANIC-MOLECULES
UR  - https://pubs.acs.org/doi/10.1021/acs.jpcc.8b03972
L2  - https://pubs.acs.org/doi/10.1021/acs.jpcc.8b03972
N2  - Naphthalene was deposited from the vapor phase on ice surfaces at 77 or 253 K to yield strongly distinct behavior, forming either an amorphous glass layer or submicrometer-sized crystals, respectively. The results stand upon optical emission spectroscopy combined with differential scanning calorimetry and X-ray analysis. The amorphous layer of naphthalene on the ice behaves in the same manner as on an inert metallic support: it starts to relax at 105 K and crystallizes at 185 K. The formed microcrystals exhibit distinct absorption behavior on the ice surface and are thus expected to have a photokinetic profile varying from freeze-concentrated solutions. The observations bring implications toward environmental and extraterrestrial ice sciences.
ER  -

ONDRUŠKOVÁ, Gabriela, Ján KRAUSKO, Josef N. STERN, Astrid HAUPTMANN, Thomas LOERTING and Dominik HEGER. Distinct Speciation of Naphthalene Vapor Deposited on Ice Surfaces at 253 or 77 K: Formation of Submicrometer-Sized Crystals or an Amorphous Layer. \textit{Journal of Physical Chemistry C}. Washington D.C.: American Chemical Society, 2018, vol.~122, No~22, p.~11945-11953. ISSN~1932-7447. Available from: https://dx.doi.org/10.1021/acs.jpcc.8b03972.

Detailed Information on Publication Record