| KOLLHAMMEROVÁ, Iva, Michal BABIAK, Marek NEČAS, Petr TÁBORSKÝ, Josef KUČERA and Jiří PINKAS. Alumazene Reactivity with Quinolinols - Addition and Substitution Reactions on the Al3N3 Ring. Acta Chimica Slovenica. LJUBLJANA: SLOVENSKO KEMIJSKO DRUSTVO, 2018, vol. 65, No 4, p. 955-963. ISSN 1318-0207. Available from: https://dx.doi.org/10.17344/acsi.2018.4624. |
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@article{1504916,
author = {Kollhammerová, Iva and Babiak, Michal and Nečas, Marek and Táborský, Petr and Kučera, Josef and Pinkas, Jiří},
article_location = {LJUBLJANA},
article_number = {4},
doi = {http://dx.doi.org/10.17344/acsi.2018.4624},
keywords = {Alumazene; crystal structure; quinolin-8-ol; 2-methylquinolin-8-ol; luminescence},
language = {eng},
issn = {1318-0207},
journal = {Acta Chimica Slovenica},
title = {Alumazene Reactivity with Quinolinols - Addition and Substitution Reactions on the Al3N3 Ring},
url = {http://dx.doi.org/10.17344/acsi.2018.4624},
volume = {65},
year = {2018}
}
TY - JOUR
ID - 1504916
AU - Kollhammerová, Iva - Babiak, Michal - Nečas, Marek - Táborský, Petr - Kučera, Josef - Pinkas, Jiří
PY - 2018
TI - Alumazene Reactivity with Quinolinols - Addition and Substitution Reactions on the Al3N3 Ring
JF - Acta Chimica Slovenica
VL - 65
IS - 4
SP - 955-963
EP - 955-963
PB - SLOVENSKO KEMIJSKO DRUSTVO
SN - 13180207
KW - Alumazene
KW - crystal structure
KW - quinolin-8-ol
KW - 2-methylquinolin-8-ol
KW - luminescence
UR - http://dx.doi.org/10.17344/acsi.2018.4624
N2 - Molecular structures of two compounds obtained in reactions of alumazene [DippNAIMe](3) (1, Dipp = 2,6-i-Pr2C6H3) with substituted quinolinols have been elucidated by the single-crystal X-ray diffraction analysis. Quinolin-8-ol (Hq) provides a dinuclear complex [(DippNH)(2)Al2Me2(q)(2)] (2) with a central Al2O2 ring and five-coordinate Al atoms. The compound 2 center dot THF crystallizes in the orthorhombic Pbca space group. The molecular structure of a mononuclear complex [(DippNH)Al(Meq)(2)] (3) obtained in the reaction of 1 with 2-methylquinolin-8-ol (HMeq) possesses a five-coordinate Al center. The structure was solved in a triclinic cell P-1. The dinuclear complex 2 can be considered as a model product of alcohol addition on the formal Al-N double bond, while the mononuclear complex 3 represents subsequent reaction of remaining Al-Me moiety with proton. Both complexes 2 and 3 are highly luminescent showing emission around 500 nm in solid state.
ER -
KOLLHAMMEROVÁ, Iva, Michal BABIAK, Marek NEČAS, Petr TÁBORSKÝ, Josef KUČERA and Jiří PINKAS. Alumazene Reactivity with Quinolinols - Addition and Substitution Reactions on the Al3N3 Ring. \textit{Acta Chimica Slovenica}. LJUBLJANA: SLOVENSKO KEMIJSKO DRUSTVO, 2018, vol.~65, No~4, p.~955-963. ISSN~1318-0207. Available from: https://dx.doi.org/10.17344/acsi.2018.4624.
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