Alumazene Reactivity with Quinolinols - Addition and
Substitution Reactions on the Al3N3 Ring

J 2018

Alumazene Reactivity with Quinolinols - Addition and Substitution Reactions on the Al3N3 Ring

KOLLHAMMEROVÁ, Iva, Michal BABIAK, Marek NEČAS, Petr TÁBORSKÝ, Josef KUČERA et. al.

Basic information

Original name

Alumazene Reactivity with Quinolinols - Addition and Substitution Reactions on the Al3N3 Ring

Authors

KOLLHAMMEROVÁ, Iva (203 Czech Republic, belonging to the institution), Michal BABIAK (703 Slovakia, belonging to the institution), Marek NEČAS (203 Czech Republic, belonging to the institution), Petr TÁBORSKÝ (203 Czech Republic, belonging to the institution), Josef KUČERA (203 Czech Republic, belonging to the institution) and Jiří PINKAS (203 Czech Republic, guarantor, belonging to the institution)

Edition

Acta Chimica Slovenica, LJUBLJANA, SLOVENSKO KEMIJSKO DRUSTVO, 2018, 1318-0207

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10400 1.4 Chemical sciences

Country of publisher

Slovenia

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Impact factor

Impact factor: 1.076

RIV identification code

RIV/00216224:14310/18:00106568

Organization unit

Faculty of Science

DOI

http://dx.doi.org/10.17344/acsi.2018.4624

UT WoS

000453240200020

Keywords in English

Alumazene; crystal structure; quinolin-8-ol; 2-methylquinolin-8-ol; luminescence

Abstract

V originále

Molecular structures of two compounds obtained in reactions of alumazene [DippNAIMe](3) (1, Dipp = 2,6-i-Pr2C6H3) with substituted quinolinols have been elucidated by the single-crystal X-ray diffraction analysis. Quinolin-8-ol (Hq) provides a dinuclear complex [(DippNH)(2)Al2Me2(q)(2)] (2) with a central Al2O2 ring and five-coordinate Al atoms. The compound 2 center dot THF crystallizes in the orthorhombic Pbca space group. The molecular structure of a mononuclear complex [(DippNH)Al(Meq)(2)] (3) obtained in the reaction of 1 with 2-methylquinolin-8-ol (HMeq) possesses a five-coordinate Al center. The structure was solved in a triclinic cell P-1. The dinuclear complex 2 can be considered as a model product of alcohol addition on the formal Al-N double bond, while the mononuclear complex 3 represents subsequent reaction of remaining Al-Me moiety with proton. Both complexes 2 and 3 are highly luminescent showing emission around 500 nm in solid state.

Links

LM2015043, research and development project

Name: Česká infrastruktura pro integrativní strukturní biologii (Acronym: CIISB)

Investor: Ministry of Education, Youth and Sports of the CR

LQ1601, research and development project

Name: CEITEC 2020 (Acronym: CEITEC2020)

Investor: Ministry of Education, Youth and Sports of the CR

Citovat

KOLLHAMMEROVÁ, Iva, Michal BABIAK, Marek NEČAS, Petr TÁBORSKÝ, Josef KUČERA and Jiří PINKAS. Alumazene Reactivity with Quinolinols - Addition and Substitution Reactions on the Al3N3 Ring. Acta Chimica Slovenica. LJUBLJANA: SLOVENSKO KEMIJSKO DRUSTVO, 2018, vol. 65, No 4, p. 955-963. ISSN 1318-0207. Available from: https://dx.doi.org/10.17344/acsi.2018.4624.

@article{1504916,
   author = {Kollhammerová, Iva and Babiak, Michal and Nečas, Marek and Táborský, Petr and Kučera, Josef and Pinkas, Jiří},
   article_location = {LJUBLJANA},
   article_number = {4},
   doi = {http://dx.doi.org/10.17344/acsi.2018.4624},
   keywords = {Alumazene; crystal structure; quinolin-8-ol; 2-methylquinolin-8-ol; luminescence},
   language = {eng},
   issn = {1318-0207},
   journal = {Acta Chimica Slovenica},
   title = {Alumazene Reactivity with Quinolinols - Addition and Substitution Reactions on the Al3N3 Ring},
   url = {http://dx.doi.org/10.17344/acsi.2018.4624},
   volume = {65},
   year = {2018}
}

TY  - JOUR
ID  - 1504916
AU  - Kollhammerová, Iva - Babiak, Michal - Nečas, Marek - Táborský, Petr - Kučera, Josef - Pinkas, Jiří
PY  - 2018
TI  - Alumazene Reactivity with Quinolinols - Addition and Substitution Reactions on the Al3N3 Ring
JF  - Acta Chimica Slovenica
VL  - 65
IS  - 4
SP  - 955-963
EP  - 955-963
PB  - SLOVENSKO KEMIJSKO DRUSTVO
SN  - 13180207
KW  - Alumazene
KW  - crystal structure
KW  - quinolin-8-ol
KW  - 2-methylquinolin-8-ol
KW  - luminescence
UR  - http://dx.doi.org/10.17344/acsi.2018.4624
N2  - Molecular structures of two compounds obtained in reactions of alumazene [DippNAIMe](3) (1, Dipp = 2,6-i-Pr2C6H3) with substituted quinolinols have been elucidated by the single-crystal X-ray diffraction analysis. Quinolin-8-ol (Hq) provides a dinuclear complex [(DippNH)(2)Al2Me2(q)(2)] (2) with a central Al2O2 ring and five-coordinate Al atoms. The compound 2 center dot THF crystallizes in the orthorhombic Pbca space group. The molecular structure of a mononuclear complex [(DippNH)Al(Meq)(2)] (3) obtained in the reaction of 1 with 2-methylquinolin-8-ol (HMeq) possesses a five-coordinate Al center. The structure was solved in a triclinic cell P-1. The dinuclear complex 2 can be considered as a model product of alcohol addition on the formal Al-N double bond, while the mononuclear complex 3 represents subsequent reaction of remaining Al-Me moiety with proton. Both complexes 2 and 3 are highly luminescent showing emission around 500 nm in solid state.
ER  -

KOLLHAMMEROVÁ, Iva, Michal BABIAK, Marek NEČAS, Petr TÁBORSKÝ, Josef KUČERA and Jiří PINKAS. Alumazene Reactivity with Quinolinols - Addition and Substitution Reactions on the Al3N3 Ring. \textit{Acta Chimica Slovenica}. LJUBLJANA: SLOVENSKO KEMIJSKO DRUSTVO, 2018, vol.~65, No~4, p.~955-963. ISSN~1318-0207. Available from: https://dx.doi.org/10.17344/acsi.2018.4624.

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