The theoretical and experimental study of the Sb-Sn nano-alloys

J 2019

The theoretical and experimental study of the Sb-Sn nano-alloys

KROUPA, Aleš, Vít VYKOUKAL, Tomáš KÁŇA, Adéla ZEMANOVÁ, Jiří PINKAS et. al.

Basic information

Original name

The theoretical and experimental study of the Sb-Sn nano-alloys

Authors

KROUPA, Aleš (203 Czech Republic, guarantor), Vít VYKOUKAL (203 Czech Republic, belonging to the institution), Tomáš KÁŇA (203 Czech Republic), Adéla ZEMANOVÁ (203 Czech Republic), Jiří PINKAS (203 Czech Republic, belonging to the institution) and Mojmír ŠOB (203 Czech Republic, belonging to the institution)

Edition

CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, Oxford, PERGAMON-ELSEVIER SCIENCE, 2019, 0364-5916

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

United Kingdom of Great Britain and Northern Ireland

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Impact factor

Impact factor: 1.947

RIV identification code

RIV/00216224:14310/19:00107551

Organization unit

Faculty of Science

DOI

http://dx.doi.org/10.1016/j.calphad.2018.11.004

UT WoS

000460842600010

Keywords in English

PHASE-DIAGRAM PREDICTION; AB-INITIO; SOFTWARE; COMPLEX; SYSTEM

Abstract

V originále

The Sb-Sn nano-alloys were prepared by wet synthesis and studied experimentally and by theoretical modelling. A combination of CALPHAD and ab initio method for modelling of the influence of particle size on the thermodynamic properties and phase equilibria in systems with complex, intermetallic phases was used to model the properties of the Sb-Sn system. The disappearance of the Sb2Sn3 phase was predicted for the equilibria with the particle radius below 80 nm. The experimental study carried out on Sb-Sn nanoalloys showed that Sb2Sn3 did not appear during the 1st run of DSC measurement, when the morphology of sample contains agglomerates of nanoparticles with the radius below 50 nm.

Links

GA17-15405S, research and development project

Name: Pokročilé experimentální a teoretické přístupy k fázovým diagramům nanoslitin se zahrnutím vlivu velikosti částic

Investor: Czech Science Foundation

LM2015043, research and development project

Name: Česká infrastruktura pro integrativní strukturní biologii (Acronym: CIISB)

Investor: Ministry of Education, Youth and Sports of the CR

LQ1601, research and development project

Name: CEITEC 2020 (Acronym: CEITEC2020)

Investor: Ministry of Education, Youth and Sports of the CR

Citovat

KROUPA, Aleš, Vít VYKOUKAL, Tomáš KÁŇA, Adéla ZEMANOVÁ, Jiří PINKAS and Mojmír ŠOB. The theoretical and experimental study of the Sb-Sn nano-alloys. CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY. Oxford: PERGAMON-ELSEVIER SCIENCE, 2019, vol. 64, No 1, p. 90-96. ISSN 0364-5916. Available from: https://dx.doi.org/10.1016/j.calphad.2018.11.004.

@article{1548871,
   author = {Kroupa, Aleš and Vykoukal, Vít and Káňa, Tomáš and Zemanová, Adéla and Pinkas, Jiří and Šob, Mojmír},
   article_location = {Oxford},
   article_number = {1},
   doi = {http://dx.doi.org/10.1016/j.calphad.2018.11.004},
   keywords = {PHASE-DIAGRAM PREDICTION; AB-INITIO; SOFTWARE; COMPLEX; SYSTEM},
   language = {eng},
   issn = {0364-5916},
   journal = {CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY},
   title = {The theoretical and experimental study of the Sb-Sn nano-alloys},
   url = {http://dx.doi.org/10.1016/j.calphad.2018.11.004},
   volume = {64},
   year = {2019}
}

TY  - JOUR
ID  - 1548871
AU  - Kroupa, Aleš - Vykoukal, Vít - Káňa, Tomáš - Zemanová, Adéla - Pinkas, Jiří - Šob, Mojmír
PY  - 2019
TI  - The theoretical and experimental study of the Sb-Sn nano-alloys
JF  - CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY
VL  - 64
IS  - 1
SP  - 90-96
EP  - 90-96
PB  - PERGAMON-ELSEVIER SCIENCE
SN  - 03645916
KW  - PHASE-DIAGRAM PREDICTION
KW  - AB-INITIO
KW  - SOFTWARE
KW  - COMPLEX
KW  - SYSTEM
UR  - http://dx.doi.org/10.1016/j.calphad.2018.11.004
L2  - http://dx.doi.org/10.1016/j.calphad.2018.11.004
N2  - The Sb-Sn nano-alloys were prepared by wet synthesis and studied experimentally and by theoretical modelling. A combination of CALPHAD and ab initio method for modelling of the influence of particle size on the thermodynamic properties and phase equilibria in systems with complex, intermetallic phases was used to model the properties of the Sb-Sn system. The disappearance of the Sb2Sn3 phase was predicted for the equilibria with the particle radius below 80 nm. The experimental study carried out on Sb-Sn nanoalloys showed that Sb2Sn3 did not appear during the 1st run of DSC measurement, when the morphology of sample contains agglomerates of nanoparticles with the radius below 50 nm.
ER  -

KROUPA, Aleš, Vít VYKOUKAL, Tomáš KÁŇA, Adéla ZEMANOVÁ, Jiří PINKAS and Mojmír ŠOB. The theoretical and experimental study of the Sb-Sn nano-alloys. \textit{CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY}. Oxford: PERGAMON-ELSEVIER SCIENCE, 2019, vol.~64, No~1, p.~90-96. ISSN~0364-5916. Available from: https://dx.doi.org/10.1016/j.calphad.2018.11.004.

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