| MIRZAEI, Saeed, Mostafa ALISHAHI, Pavel SOUČEK, Jaroslav ŽENÍŠEK, David HOLEC, Nikola KOUTNÁ, Vilma BURŠÍKOVÁ, Monika STUPAVSKÁ, Lukáš ZÁBRANSKÝ, Frank BURMEISTER, Bernhard BLUG, Zsolt CZIGÁNY, Katalin BALÁZSI, Romana MIKŠOVÁ and Petr VAŠINA. The effect of chemical composition on the structure, chemistry and mechanical properties of magnetron sputtered W-B-C coatings: Modeling and experiments. Surface & coatings technology. Elsevier, 2020, vol. 383, FEB 15 2020, p. 1-12. ISSN 0257-8972. Available from: https://dx.doi.org/10.1016/j.surfcoat.2019.125274. |
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@article{1594398,
author = {Mirzaei, Saeed and Alishahi, Mostafa and Souček, Pavel and Ženíšek, Jaroslav and Holec, David and Koutná, Nikola and Buršíková, Vilma and Stupavská, Monika and Zábranský, Lukáš and Burmeister, Frank and Blug, Bernhard and Czigány, Zsolt and Balázsi, Katalin and Mikšová, Romana and Vašina, Petr},
article_number = {FEB 15 2020},
doi = {http://dx.doi.org/10.1016/j.surfcoat.2019.125274},
keywords = {Magnetron sputtering; Mechanical properties; Fracture resistance; W-B-C; Ab initio},
language = {eng},
issn = {0257-8972},
journal = {Surface & coatings technology},
title = {The effect of chemical composition on the structure, chemistry and mechanical properties of magnetron sputtered W-B-C coatings: Modeling and experiments},
url = {https://www.sciencedirect.com/science/article/pii/S0257897219312642},
volume = {383},
year = {2020}
}
TY - JOUR
ID - 1594398
AU - Mirzaei, Saeed - Alishahi, Mostafa - Souček, Pavel - Ženíšek, Jaroslav - Holec, David - Koutná, Nikola - Buršíková, Vilma - Stupavská, Monika - Zábranský, Lukáš - Burmeister, Frank - Blug, Bernhard - Czigány, Zsolt - Balázsi, Katalin - Mikšová, Romana - Vašina, Petr
PY - 2020
TI - The effect of chemical composition on the structure, chemistry and mechanical properties of magnetron sputtered W-B-C coatings: Modeling and experiments
JF - Surface & coatings technology
VL - 383
IS - FEB 15 2020
SP - 1-12
EP - 1-12
PB - Elsevier
SN - 02578972
KW - Magnetron sputtering
KW - Mechanical properties
KW - Fracture resistance
KW - W-B-C
KW - Ab initio
UR - https://www.sciencedirect.com/science/article/pii/S0257897219312642
L2 - https://www.sciencedirect.com/science/article/pii/S0257897219312642
N2 - Ternary W-B-C coatings were non-reactively deposited in order to enhance the envelope of the mechanical properties of the binary transition metal borides and carbides with a focus on fracture resistance. The study investigated the influence of the atomic composition on the chemistry, microstructure, and mechanical properties of W-B-C coatings. The content of tungsten was found to be a key parameter influencing the energy flux delivered to the growing coating and therefore influencing the structure of the coating. Increased tungsten content led to a denser structure of the coating, but also to the amorphization of the microstructure. An increase in the WB bond fraction was observed as the tungsten content increased and correspondingly, the content of carbon decreased. Increasing the ratio of stronger boride bonds associated with stiff materials with high Young's modulus such as WB resulted in the enhanced mechanical properties of the coatings. A theoretical method for the comparison of experimentally derived bonding with ab initio simulations of randomly distributed amorphous materials was proposed. The method was applicable for amorphous coatings while the coatings with WC1-x nanocrystals exhibited the greatest discrepancies between the calculated and the experimentally derived bond fractions. This indicates that our proposed model is an appropriate tool for prediction of the bonding state of amorphous coatings.
ER -
MIRZAEI, Saeed, Mostafa ALISHAHI, Pavel SOUČEK, Jaroslav ŽENÍŠEK, David HOLEC, Nikola KOUTNÁ, Vilma BURŠÍKOVÁ, Monika STUPAVSKÁ, Lukáš ZÁBRANSKÝ, Frank BURMEISTER, Bernhard BLUG, Zsolt CZIGÁNY, Katalin BALÁZSI, Romana MIKŠOVÁ and Petr VAŠINA. The effect of chemical composition on the structure, chemistry and mechanical properties of magnetron sputtered W-B-C coatings: Modeling and experiments. \textit{Surface \&{} coatings technology}. Elsevier, 2020, vol.~383, FEB 15 2020, p.~1-12. ISSN~0257-8972. Available from: https://dx.doi.org/10.1016/j.surfcoat.2019.125274.
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