Differentiation of clay-based pigments in paintings by means of
laser ablation-inductively coupled plasma-mass spectrometry

J 2019

Differentiation of clay-based pigments in paintings by means of laser ablation-inductively coupled plasma-mass spectrometry

POSPÍŠILOVÁ, Eva; David HRADIL; Markéta HOLÁ; Janka HRADILOVÁ; Karel NOVOTNÝ et. al.

Základní údaje

Originální název

Differentiation of clay-based pigments in paintings by means of laser ablation-inductively coupled plasma-mass spectrometry

Autoři

POSPÍŠILOVÁ, Eva (203 Česká republika, domácí); David HRADIL (203 Česká republika); Markéta HOLÁ (203 Česká republika, domácí); Janka HRADILOVÁ (203 Česká republika); Karel NOVOTNÝ (203 Česká republika, garant, domácí) a Viktor KANICKÝ (203 Česká republika, domácí)

Vydání

Spectrochimica Acta B, Oxford, Elsevier, 2019, 0584-8547

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10406 Analytical chemistry

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 3.086

Kód RIV

RIV/00216224:14310/19:00113152

Organizační jednotka

Přírodovědecká fakulta

DOI

https://doi.org/10.1016/j.sab.2019.105639

UT WoS

000484434900005

EID Scopus

2-s2.0-85067866111

Klíčová slova anglicky

Trace elements; LA-ICP-MS; Painting grounds; Provenance analysis; Clay pigments

Štítky

rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 28. 2. 2020 14:45, Mgr. Eva Zikmundová, Ph.D.

Anotace

V originále

The method of the laser ablation-inductively coupled plasma-mass spectrometry has become an effective tool in the analysis of the art and archaeological objects. With a few exceptions, however, it has not been fully established in the provenance analysis of historical paintings yet. Although the method is micro-destructive for the paint samples, the direct solid sample analysis with just a minor material removal enables obtaining valuable information on the trace element composition, which is useful for the track the origin of mineral pigments, as, e.g. the clay-based pigments. This work aimed for the optimization of the measurement parameters and a subsequent differentiation of red clays from three reference localities in Europe that were pre-selected based on their relevance for the 18th century painting. Finally, the ground preparatory layer from a painting by an 18th century painter, J. G. de Hamilton, has been analysed. It was satisfactorily proved that the red clay used in the ground was mined out in Troschenreuth, Bavaria, Germany. This is in line with the historical documents recording that Hamilton, when he was acting in Bohemia, bought already primed (ready-to-use) canvases in Bavaria. Despite the heterogeneity and small sizes of paint samples the obtained results show the way in which the provenance analysis of clays in paint samples can be performed. This opens up an entirely new possibility of assessing the regional provenance of historical paintings.

Návaznosti

LQ1601, projekt VaV

Název: CEITEC 2020 (Akronym: CEITEC2020)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, CEITEC 2020

MUNI/A/1288/2017, interní kód MU

Název: Výzkum, vývoj a aplikace v analytické a fyzikální chemii (Akronym: AFCH)

Investor: Masarykova univerzita, Výzkum, vývoj a aplikace v analytické a fyzikální chemii, DO R. 2020_Kategorie A - Specifický výzkum - Studentské výzkumné projekty

Citovat

POSPÍŠILOVÁ, Eva; David HRADIL; Markéta HOLÁ; Janka HRADILOVÁ; Karel NOVOTNÝ a Viktor KANICKÝ. Differentiation of clay-based pigments in paintings by means of laser ablation-inductively coupled plasma-mass spectrometry. Spectrochimica Acta B. Oxford: Elsevier, 2019, roč. 158, AUG, s. 105639-105649. ISSN 0584-8547. Dostupné z: https://doi.org/10.1016/j.sab.2019.105639.

@article{1629681,
   author = {Pospíšilová, Eva and Hradil, David and Holá, Markéta and Hradilová, Janka and Novotný, Karel and Kanický, Viktor},
   article_location = {Oxford},
   article_number = {AUG},
   doi = {https://doi.org/10.1016/j.sab.2019.105639},
   keywords = {Trace elements; LA-ICP-MS; Painting grounds; Provenance analysis; Clay pigments},
   language = {eng},
   issn = {0584-8547},
   journal = {Spectrochimica Acta B},
   title = {Differentiation of clay-based pigments in paintings by means of laser ablation-inductively coupled plasma-mass spectrometry},
   url = {https://www.sciencedirect.com/science/article/pii/S0584854719301648},
   volume = {158},
   year = {2019}
}

TY  - JOUR
ID  - 1629681
AU  - Pospíšilová, Eva - Hradil, David - Holá, Markéta - Hradilová, Janka - Novotný, Karel - Kanický, Viktor
PY  - 2019
TI  - Differentiation of clay-based pigments in paintings by means of laser ablation-inductively coupled plasma-mass spectrometry
JF  - Spectrochimica Acta B
VL  - 158
IS  - AUG
SP  - 105639
EP  - 105639
PB  - Elsevier
SN  - 05848547
KW  - Trace elements
KW  - LA-ICP-MS
KW  - Painting grounds
KW  - Provenance analysis
KW  - Clay pigments
UR  - https://www.sciencedirect.com/science/article/pii/S0584854719301648
L2  - https://www.sciencedirect.com/science/article/pii/S0584854719301648
N2  - The method of the laser ablation-inductively coupled plasma-mass spectrometry has become an effective tool in the analysis of the art and archaeological objects. With a few exceptions, however, it has not been fully established in the provenance analysis of historical paintings yet. Although the method is micro-destructive for the paint samples, the direct solid sample analysis with just a minor material removal enables obtaining valuable information on the trace element composition, which is useful for the track the origin of mineral pigments, as, e.g. the clay-based pigments. This work aimed for the optimization of the measurement parameters and a subsequent differentiation of red clays from three reference localities in Europe that were pre-selected based on their relevance for the 18th century painting. Finally, the ground preparatory layer from a painting by an 18th century painter, J. G. de Hamilton, has been analysed. It was satisfactorily proved that the red clay used in the ground was mined out in Troschenreuth, Bavaria, Germany. This is in line with the historical documents recording that Hamilton, when he was acting in Bohemia, bought already primed (ready-to-use) canvases in Bavaria. Despite the heterogeneity and small sizes of paint samples the obtained results show the way in which the provenance analysis of clays in paint samples can be performed. This opens up an entirely new possibility of assessing the regional provenance of historical paintings.
ER  -

POSPÍŠILOVÁ, Eva; David HRADIL; Markéta HOLÁ; Janka HRADILOVÁ; Karel NOVOTNÝ a Viktor KANICKÝ. Differentiation of clay-based pigments in paintings by means of laser ablation-inductively coupled plasma-mass spectrometry. \textit{Spectrochimica Acta B}. Oxford: Elsevier, 2019, roč.~158, AUG, s.~105639-105649. ISSN~0584-8547. Dostupné z: https://doi.org/10.1016/j.sab.2019.105639.

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