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@article{1670344,
author = {Mrlik, M. and Špírek, Mário and AlandKhori, J. and Ahmad, A. A. and Mosnacek, J. and AlMaadeed, M. A. and Kasak, P.},
article_location = {Amsterdam},
article_number = {1},
doi = {http://dx.doi.org/10.1016/j.arabjc.2017.03.009},
keywords = {Polysulfobetaine; Metal coordination; Antibacterial; Self-healing; Hydrogels; Catecholamine polymers},
language = {eng},
issn = {1878-5352},
journal = {Arabian Journal of Chemistry},
title = {Mussel-mimicking sulfobetaine-based copolymer with metal tunable gelation, self-healing and antibacterial capability},
url = {https://www.sciencedirect.com/science/article/pii/S1878535217300679?via%3Dihub},
volume = {13},
year = {2020}
}
TY - JOUR
ID - 1670344
AU - Mrlik, M. - Špírek, Mário - Al-Khori, J. - Ahmad, A. A. - Mosnacek, J. - AlMaadeed, M. A. - Kasak, P.
PY - 2020
TI - Mussel-mimicking sulfobetaine-based copolymer with metal tunable gelation, self-healing and antibacterial capability
JF - Arabian Journal of Chemistry
VL - 13
IS - 1
SP - 193-204
EP - 193-204
PB - ELSEVIER
SN - 18785352
KW - Polysulfobetaine
KW - Metal coordination
KW - Antibacterial
KW - Self-healing
KW - Hydrogels
KW - Catecholamine polymers
UR - https://www.sciencedirect.com/science/article/pii/S1878535217300679?via%3Dihub
L2 - https://www.sciencedirect.com/science/article/pii/S1878535217300679?via%3Dihub
N2 - In the present study, the sulfobetaine-based copolymer bearing a dopamine functionality showed gel formation adjusted by the application of metal salts for gelation and various values of pH. Normally, the liquid-like solution of the sulfobetaine-based copolymer and metal cross-linkers is transformed to a gel-like state upon increasing the pH values in the presence of Fe3+ and Ti3+. Metal-induced coordination is reversible by means of the application of EDTA as a chelating agent. In the case of Ag+ ions, the gel is formed through a redox process accompanied with the oxidative coupling of the dopamine moieties and Ag-0 particle formation. Mussel-mimicking and metal-dependent viscoelastic properties were observed for Fe3+, Ti3+, and Ag+ cross-linking agents, with additionally enhanced self-healing behavior in comparison with the covalently cross-linked IO4- analogues. Antibacterial properties can be achieved both in solution and on the surface using the proper concentration of Ag+ ions used for gelation; thus, a tunable amount of the Ag-0 particles are formed in the hydrogel. The cytotoxicity was elucidated by the both MTT assay on the NIH/3T3 fibroblast cell line and direct contact method using human dermal fibroblast cell (F121) and shows the non-toxic character of the synthesized copolymer. (C) 2017 The Authors. Production and hosting by Elsevier B.V. on behalf of King Saud University.
ER -
MRLIK, M., Mário ŠPÍREK, J. AL-KHORI, A. A. AHMAD, J. MOSNACEK, M. A. ALMAADEED and P. KASAK. Mussel-mimicking sulfobetaine-based copolymer with metal tunable gelation, self-healing and antibacterial capability. \textit{Arabian Journal of Chemistry}. Amsterdam: ELSEVIER, 2020, vol.~13, No~1, p.~193-204. ISSN~1878-5352. Available from: https://dx.doi.org/10.1016/j.arabjc.2017.03.009.
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