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@article{1693576,
author = {Salajková, Zita and Holá, Markéta and Procházka, David and Ondráček, Jakub and Pavliňák, David and Čelko, Ladislav and Gregar, Filip and Šperka, Petr and Pořízka, Pavel and Kanický, Viktor and De Giacomo, Alessandro and Kaiser, Jozef},
article_location = {Amsterdam},
article_number = {January 2021},
doi = {http://dx.doi.org/10.1016/j.talanta.2020.121512},
keywords = {Laser ablation; LA-ICP-MS; Surface analysis; Surface topography; Fractionation},
language = {eng},
issn = {0039-9140},
journal = {Talanta},
title = {Influence of sample surface topography on laser ablation process},
url = {https://www.sciencedirect.com/science/article/pii/S0039914020308031},
volume = {222},
year = {2021}
}
TY - JOUR
ID - 1693576
AU - Salajková, Zita - Holá, Markéta - Procházka, David - Ondráček, Jakub - Pavliňák, David - Čelko, Ladislav - Gregar, Filip - Šperka, Petr - Pořízka, Pavel - Kanický, Viktor - De Giacomo, Alessandro - Kaiser, Jozef
PY - 2021
TI - Influence of sample surface topography on laser ablation process
JF - Talanta
VL - 222
IS - January 2021
SP - 1-9
EP - 1-9
PB - Elsevier
SN - 00399140
KW - Laser ablation
KW - LA-ICP-MS
KW - Surface analysis
KW - Surface topography
KW - Fractionation
UR - https://www.sciencedirect.com/science/article/pii/S0039914020308031
L2 - https://www.sciencedirect.com/science/article/pii/S0039914020308031
N2 - In this work we discuss how sample surface topography can significantly influence the laser ablation (LA) process and, in turn, the analytical response of the LA Inductively Coupled Plasma Mass Spectrometr y (LA-ICP-MS) method. Six different surface topographies were prepared on a certified aluminiu m alloy sample BAM 311 and SRM NIST 610 to investigate the phenomenon. A l l the samples were repetitively measured by LA-ICP-MS using a spot by spot analysis. The effect oflaserfluence in the range of 1-13 J/cm(2) was studied . For majority ofmeasured isotopes, the ICP-MS signal was amplified with roughening of the sample surface. A stronger effect was observed on the Al alloy sample, where the more than sixty-time enhancement was achieved in comparison to the polished surface of the sample. Since the effect of surface topography is different for each analyte, it can be stated that surface properties affect not only the ICP-MS response, but also elemental fractionation in LA . The presented results show that different surface topographies may lead to misleading data interpretation because even when applying ablation preshots, the signal of individual elements changes. The utmost care must be taken when preparing the surface for single shot analysis or chemical mapping. On the other hand, by roughening the sample surface, it is possible to significantly increase the sensitivity of the method for individual analytes and supress a matrix effect.
ER -
SALAJKOVÁ, Zita, Markéta HOLÁ, David PROCHÁZKA, Jakub ONDRÁČEK, David PAVLIŇÁK, Ladislav ČELKO, Filip GREGAR, Petr ŠPERKA, Pavel POŘÍZKA, Viktor KANICKÝ, Alessandro DE GIACOMO and Jozef KAISER. Influence of sample surface topography on laser ablation process. \textit{Talanta}. Amsterdam: Elsevier, 2021, vol.~222, January 2021, p.~1-9. ISSN~0039-9140. Available from: https://dx.doi.org/10.1016/j.talanta.2020.121512.
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