| BELOVA, Valentina, Alexander HINDERHOFER, Clemens ZEISER, Timo STORZER, Jakub ROZBOŘIL, Jan HAGENLOCHER, Jiří NOVÁK, Alexander GERLACH, Reinhard SCHOLZ and Frank SCHREIBER. Structure-Dependent Charge Transfer in Molecular Perylene-Based Donor/Acceptor Systems and Role of Side Chains. Journal of Physical Chemistry C. Washington D.C.: American Chemical Society, 2020, vol. 124, No 21, p. 11639-11651. ISSN 1932-7447. Available from: https://dx.doi.org/10.1021/acs.jpcc.0c00230. |
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@article{1710956,
author = {Belova, Valentina and Hinderhofer, Alexander and Zeiser, Clemens and Storzer, Timo and Rozbořil, Jakub and Hagenlocher, Jan and Novák, Jiří and Gerlach, Alexander and Scholz, Reinhard and Schreiber, Frank},
article_location = {Washington D.C.},
article_number = {21},
doi = {http://dx.doi.org/10.1021/acs.jpcc.0c00230},
keywords = {Mixtures; Thin films; Energy; Molecular interactions; Molecules},
language = {eng},
issn = {1932-7447},
journal = {Journal of Physical Chemistry C},
title = {Structure-Dependent Charge Transfer in Molecular Perylene-Based Donor/Acceptor Systems and Role of Side Chains},
url = {https://doi.org/10.1021/acs.jpcc.0c00230},
volume = {124},
year = {2020}
}
TY - JOUR
ID - 1710956
AU - Belova, Valentina - Hinderhofer, Alexander - Zeiser, Clemens - Storzer, Timo - Rozbořil, Jakub - Hagenlocher, Jan - Novák, Jiří - Gerlach, Alexander - Scholz, Reinhard - Schreiber, Frank
PY - 2020
TI - Structure-Dependent Charge Transfer in Molecular Perylene-Based Donor/Acceptor Systems and Role of Side Chains
JF - Journal of Physical Chemistry C
VL - 124
IS - 21
SP - 11639-11651
EP - 11639-11651
PB - American Chemical Society
SN - 19327447
KW - Mixtures
KW - Thin films
KW - Energy
KW - Molecular interactions
KW - Molecules
UR - https://doi.org/10.1021/acs.jpcc.0c00230
L2 - https://doi.org/10.1021/acs.jpcc.0c00230
N2 - In organic electronics and optoelectronics several crucial physical processes are related to charge transfer (CT) effects. In this work, we investigate mixing behavior and intermolecular coupling of donor and acceptor molecules in thin films prepared by organic molecular beam deposition (OMBD). Diindenoperylene (DIP) and pentacene (PEN) are used as the donor materials, and perylene diimide derivatives PDIR-CN2 and PDIF-CN2 as the acceptor materials.. The formation of charge transfer complexes coupled in the electronic excited state vs. noninteracting phase separating components is studied by structural and optical techniques. The CT mechanism and properties are considered in close connection with the thin film microstructure of the D/A blends which can be controlled via a change of the molecule geometry and/or growth temperature. We discuss two key findings for our systems: (1) The CT intensity correlates directly with the possibility of cocrystallization between acceptor and donor. (2) Side chain modification to tune the ground state energy levels has nearly no effect on the energy of the excited state CT, whereas replacement of molecular core modifies the CT energy correspondingly.
ER -
BELOVA, Valentina, Alexander HINDERHOFER, Clemens ZEISER, Timo STORZER, Jakub ROZBOŘIL, Jan HAGENLOCHER, Jiří NOVÁK, Alexander GERLACH, Reinhard SCHOLZ and Frank SCHREIBER. Structure-Dependent Charge Transfer in Molecular Perylene-Based Donor/Acceptor Systems and Role of Side Chains. \textit{Journal of Physical Chemistry C}. Washington D.C.: American Chemical Society, 2020, vol.~124, No~21, p.~11639-11651. ISSN~1932-7447. Available from: https://dx.doi.org/10.1021/acs.jpcc.0c00230.
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