NEJDL, L., K. ZEMANKOVA, M. HAVLIKOVA, M. BURESOVA, D. HYNEK, K. XHAXHIU, F. MRAVEC, M. MATOUSKOVA, V. ADAM, M. FERUS, J. KAPUS and M. VACULOVICOVA. UV-Induced Nanoparticles-Formation, Properties and Their Potential Role in Origin of Life. NANOMATERIALS. USA: Hindawi Publishing Corporation, 2020, vol. 10, No 8, p. 1529-1542. ISSN 2079-4991. Available from: https://dx.doi.org/10.3390/nano10081529.
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Basic information
Original name UV-Induced Nanoparticles-Formation, Properties and Their Potential Role in Origin of Life
Authors NEJDL, L., K. ZEMANKOVA, M. HAVLIKOVA, M. BURESOVA, D. HYNEK, K. XHAXHIU, F. MRAVEC, M. MATOUSKOVA, V. ADAM, M. FERUS, J. KAPUS and M. VACULOVICOVA.
Edition NANOMATERIALS, USA, Hindawi Publishing Corporation, 2020, 2079-4991.
Other information
Original language English
Type of outcome Article in a journal
Field of Study 10403 Physical chemistry
Country of publisher Switzerland
Confidentiality degree is not subject to a state or trade secret
WWW URL
Impact factor Impact factor: 5.076
RIV identification code RIV/00216224:14740/20:00121455
Organization unit Central European Institute of Technology
Doi http://dx.doi.org/10.3390/nano10081529
UT WoS 000564810900001
Keywords in English UV-induced nanoparticles; origin of life; metal ions; thiols; nanoparticle-based world; nanozymes
Tags ne MU, rivok
Tags International impact, Reviewed
Changed by Changed by: Mgr. Pavla Foltynová, Ph.D., učo 106624. Changed: 12/5/2021 12:58.
Abstract
Inorganic nanoparticles might have played a vital role in the transition from inorganic chemistry to self-sustaining living systems. Such transition may have been triggered or controlled by processes requiring not only versatile catalysts but also suitable reaction surfaces. Here, experimental results showing that multicolor quantum dots might have been able to participate as catalysts in several specific and nonspecific reactions, relevant to the prebiotic chemistry are demonstrated. A very fast and easy UV-induced formation of ZnCd quantum dots (QDs) with a quantum yield of up to 47% was shown to occur 5 min after UV exposure of the solution containing Zn(II) and Cd(II) in the presence of a thiol capping agent. In addition to QDs formation, xanthine activity was observed in the solution. The role of solar radiation to induce ZnCd QDs formation was replicated during a stratospheric balloon flight.
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