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@article{1789819,
author = {Hamacek, Josef and Sokolov, Jan and Šindelář, Vladimír},
article_location = {WEINHEIM},
article_number = {17},
doi = {http://dx.doi.org/10.1002/chem.202005140},
keywords = {anion binding; bambusuril; chiral reagents; europium; helicates},
language = {eng},
issn = {0947-6539},
journal = {Chemistry - A European Journal},
title = {Bambusuril Macrocycles as Mediators of Supramolecular Interactions: Application to the Europium Cage Helicate},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202005140},
volume = {27},
year = {2021}
}
TY - JOUR
ID - 1789819
AU - Hamacek, Josef - Sokolov, Jan - Šindelář, Vladimír
PY - 2021
TI - Bambusuril Macrocycles as Mediators of Supramolecular Interactions: Application to the Europium Cage Helicate
JF - Chemistry - A European Journal
VL - 27
IS - 17
SP - 5492-5497
EP - 5492-5497
PB - Wiley
SN - 09476539
KW - anion binding
KW - bambusuril
KW - chiral reagents
KW - europium
KW - helicates
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202005140
N2 - Herein, it is shown how bambusurils can be used for tuning and/or characterizing supramolecular systems. Indeed, the addition of bambusurils as anion scavengers to metal-mediated self-assemblies allows manipulation of the subtle equilibria in the given system. This is demonstrated for the case of the tetranuclear europium helical cage, which is well suited to different applications. Among the reported results, experimental evidence is provided showing that perchlorate and triflate anions act as a molecular template for the cage assembly. The complexation of inorganic anions with neutral bambusurils resulted in bulky non-coordinating counterions that may trigger the self-assembly process or stimulate specific interactions between components. Moreover, bambusuril was able to selectively remove coordinating nitrates from the mixture with non-coordinating anions, enabling the regeneration of the helical cage.
ER -
HAMACEK, Josef, Jan SOKOLOV and Vladimír ŠINDELÁŘ. Bambusuril Macrocycles as Mediators of Supramolecular Interactions: Application to the Europium Cage Helicate. \textit{Chemistry - A European Journal}. WEINHEIM: Wiley, 2021, vol.~27, No~17, p.~5492-5497. ISSN~0947-6539. Available from: https://dx.doi.org/10.1002/chem.202005140.
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